Hydroosmiation of allenes and reductive elimination of olefin in unsaturated osmium(IV) polyhydrides: Hydride versus chloride
作者： Miguel A. Esteruelas , Carmen Larramona , Enrique Oñate
DOI: 10.1021/OM400041M
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摘要: Financial support from the Spanish MICINN (Projects CTQ2011-23459 and Consolider Ingenio 2010 (CSD2007-00006)), DGA (E35), European Social Fund (FSE) is acknowledged. We thank Centro de Supercomputacion Galicia (CESGA) for generous allocation of computational resources.
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Dmitry V. Yandulov, John C. Bollinger, William E. Streib, Kenneth G. Caulton, Os(H)2NO(PiPr3)2+: Mechanism and Energetics of a Room Temperature Reversible Ethyl/Hydridoethylene Equilibrium and Contrasting Double Insertion of Acetylene Organometallics. ,vol. 20, pp. 2040- 2046 ,(2001) , 10.1021/OM000901G
Gregory G. Hlatky, Robert H. Crabtree, Transition-metal polyhydride complexes Coordination Chemistry Reviews. ,vol. 65, pp. 1- 48 ,(1985) , 10.1016/0010-8545(85)85020-7
Dawn M. Crumpton-Bregel, Karen I. Goldberg, Mechanisms of C-C and C-H alkane reductive eliminations from octahedral Pt(IV): reaction via five-coordinate intermediates or direct elimination? Journal of the American Chemical Society. ,vol. 125, pp. 9442- 9456 ,(2003) , 10.1021/JA029140U
Miguel A. Esteruelas, Francisco J. Fernández-Alvarez, Enrique Oñate, NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism Organometallics. ,vol. 27, pp. 6236- 6244 ,(2008) , 10.1021/OM8007772
Miguel A. Esteruelas, Israel Fernández, Ana M. López, Malka Mora, Enrique Oñate, Preparation, Structure, Bonding, and Preliminary Reactivity of a Six-Coordinate d4 Osmium–Boryl Complex Organometallics. ,vol. 31, pp. 4646- 4649 ,(2012) , 10.1021/OM300407D
Olga Crespo, Beatriz Eguillor, Miguel A. Esteruelas, Israel Fernández, Jorge García-Raboso, Mar Gómez-Gallego, Mamen Martín-Ortiz, Montserrat Oliván, Miguel A. Sierra, Synthesis and characterisation of [6]-azaosmahelicenes: the first d4-heterometallahelicenes Chemical Communications. ,vol. 48, pp. 5328- 5330 ,(2012) , 10.1039/C2CC30356F
Patricia A. Maltby, Marcel Schlaf, Martin Steinbeck, Alan J. Lough, Robert H. Morris, Wim T. Klooster, Thomas F. Koetzle, Ramesh C. Srivastava, Dihydrogen with Frequency of Motion Near the 1H Larmor Frequency. Solid-State Structures and Solution NMR Spectroscopy of Osmium Complexes trans-[Os(H··H)X(PPh2CH2CH2PPh2)2]+ (X = Cl, Br) Journal of the American Chemical Society. ,vol. 118, pp. 5396- 5407 ,(1996) , 10.1021/JA9529044
Miguel A. Esteruelas, Jorge García-Raboso, Montserrat Oliván, Preparation of Half-Sandwich Osmium Complexes by Deprotonation of Aromatic and Pro-aromatic Acids with a Hexahydride Brønsted Base Organometallics. ,vol. 30, pp. 3844- 3852 ,(2011) , 10.1021/OM200371R
Peng Xue, Jun Zhu, Herman S. Y. Hung, Ian D. Williams, Zhenyang Lin, Guochen Jia, Insertion reactions of allenes giving vinyl complexes Organometallics. ,vol. 24, pp. 4896- 4898 ,(2005) , 10.1021/OM0506825
Susan M. Kloek, Karen I. Goldberg, Competitive C−H Bond Activation and β-Hydride Elimination at Platinum(II) Journal of the American Chemical Society. ,vol. 129, pp. 3460- 3461 ,(2007) , 10.1021/JA0669629