Synthesis of α-Substituted Enoximes with Nucleophiles via Nitrosoallenes
作者： Yasuhiro Nishiyama , Kiyomi Kakiuchi , Hiroki Tanimoto , Keiichi Yokoyama , Yusuke Mizutani
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摘要: This paper reports nitrosoallene-mediated synthesis of α-substituted enoximes. Nucleophilic substitution nitrosoallenes, a novel chemical species prepared from allenyl N-hydroxysulfonamides, afforded α-functionalized Introduction various nucleophiles proceeded smoothly to form C–N, C–O, C–S, C–F, and C–C bonds in the presence azodicarboxylates.
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