Surface modification of cellulose nanocrystals (CNC) by a cationic surfactant

作者: Alireza Kaboorani , Bernard Riedl

DOI: 10.1016/J.INDCROP.2014.11.027

关键词:

摘要: Surface modification of cellulose nanocrystals (CNC) is very important to explore new applications for these CNC. In this study, a cationic surfactant, hexadecyltrimethylammonium (HDTMA) bromide, was used modify the surface Chemical and structural characterizations CNC were conducted before after modification. Results revealed that chemical reaction with HDTMA led presence groups (CH2, CH3 quaternary ammonium groups) on Experiments by X-ray diffraction indicated no change in crystalline structure as result Modified had different suspension stabilities dispersibility compared unmodified The results study demonstrated can be simple straightforward negative effects

参考文章(28)
Merima Hasani, Emily D. Cranston, Gunnar Westman, Derek G. Gray, Cationic surface functionalization of cellulose nanocrystals Soft Matter. ,vol. 4, pp. 2238- 2244 ,(2008) , 10.1039/B806789A
Zhaohui Li, Robert S. Bowman, Sorption of Perchloroethylene by Surfactant-Modified Zeolite as Controlled by Surfactant Loading Environmental Science & Technology. ,vol. 32, pp. 2278- 2282 ,(1998) , 10.1021/ES971118R
W.F. Jaynes, S.A. Boyd, Clay Mineral Type and Organic Compound Sorption by Hexadecyltrimethlyammonium-Exchanged Clays Soil Science Society of America Journal. ,vol. 55, pp. 43- 48 ,(1991) , 10.2136/SSSAJ1991.03615995005500010007X
Qunxing Xu, Jie Yi, Xuefei Zhang, Hailiang Zhang, A novel amphotropic polymer based on cellulose nanocrystals grafted with azo polymers European Polymer Journal. ,vol. 44, pp. 2830- 2837 ,(2008) , 10.1016/J.EURPOLYMJ.2008.06.010
Masuduz Zaman, Huining Xiao, Felipe Chibante, Yonghao Ni, Synthesis and characterization of cationically modified nanocrystalline cellulose Carbohydrate Polymers. ,vol. 89, pp. 163- 170 ,(2012) , 10.1016/J.CARBPOL.2012.02.066
V Favier, H Chanzy, JrY Cavaillé, None, Polymer Nanocomposites Reinforced by Cellulose Whiskers Macromolecules. ,vol. 28, pp. 6365- 6367 ,(1995) , 10.1021/MA00122A053
Michaela Salajková, Lars A. Berglund, Qi Zhou, Hydrophobic cellulose nanocrystals modified with quaternary ammonium salts Journal of Materials Chemistry. ,vol. 22, pp. 19798- 19805 ,(2012) , 10.1039/C2JM34355J
Julia. Wagner, Hua. Chen, Bruce J. Brownawell, John C. Westall, Use of cationic surfactants to modify soil surfaces to promote sorption and retard migration of hydrophobic organic compounds Environmental Science & Technology. ,vol. 28, pp. 231- 237 ,(1994) , 10.1021/ES00051A008
David Dubief, Eric Samain, Alain Dufresne, Polysaccharide Microcrystals Reinforced Amorphous Poly(β-hydroxyoctanoate) Nanocomposite Materials Macromolecules. ,vol. 32, pp. 5765- 5771 ,(1999) , 10.1021/MA990274A