Improvement of reversible photoelectrochromic reaction of polyaniline in polyelectrolyte composite film with the dichloroethane solution system
作者： Yeji Kim , Kenjiro Teshima , Norihisa Kobayashi
DOI: 10.1016/S0013-4686(99)00373-4
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摘要: Abstract Photorewritable conducting polyaniline (PAn) image was successfully obtained by the photopolymerization of aniline derivatives with Flemion polyelectrolyte composite film containing Ru(bpy) 3 2+ and TiO 2 . The can be erased regenerated consecutive photoreduction photooxidation via photoinduced electron transfer for in film, respectively. These reactions were considerably affected deaeration condition reaction solution. When carried out solution deaerated O N , respectively, good reversibility on present system. However, decomposition PAn observed excessive acidic aqueous due to hydrolysis PAn. In order prevent decomposition, photoredox investigated dichloroethane CF COOH MeOH. Consequently, improvement efficiency, as well inhibition obtained.
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