Copper phthalocyanine‐titanium oxide multilayers

作者: J. Takada , H. Awaji , M. Koshioka , W. A. Nevin , M. Imanishi

DOI: 10.1063/1.356029

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摘要: Copper phthalocyanine‐titanium oxide (CuPc‐TiOx) heteromultilayers have been fabricated by evaporation and reactive techniques, their structural optoelectronic properties investigated. X‐ray diffraction secondary ion mass spectroscopy confirm the formation of a clear alternating layered structure on nanometer scale. An interface roughness 7 A has achieved for multilayer with an artificial period 40 A. Atomic force microscopy at scratched edges multilayers reveal double‐layered structures TiOx CuPc, indicating existence two kinds interface. Transverse photoconduction measurements samples deposited SnO2‐coated glass, using back electrode Al, show occurrence electron transfer from CuPc to interfaces.

参考文章(5)
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
W. A. Nevin, M. R. Hempstead, W. Liu, C. C. Leznoff, A. B. P. Lever, Electrochemistry and spectroelectrochemistry of mononuclear and binuclear cobalt phthalocyanines Inorganic Chemistry. ,vol. 26, pp. 570- 577 ,(1987) , 10.1021/IC00251A017
M.K. Debe, R.J. Poirier, K.K. Kam, Organic-thin-film-induced molecular epitaxy from the vapor phase Thin Solid Films. ,vol. 197, pp. 335- 347 ,(1991) , 10.1016/0040-6090(91)90244-R
J. Takada, H. Awaji, M. Koshioka, A. Nakajima, W. A. Nevin, Organic–inorganic multilayers: A new concept of optoelectronic material Applied Physics Letters. ,vol. 61, pp. 2184- 2186 ,(1992) , 10.1063/1.108289
Z. Kotler, R. Masse, R. Hierle, D. Josse, J. Zyss, Quadratic nonlinear-optical properties of a new transparent and highly efficient organic–inorganic crystal: 2-amino-5-nitropyridinium-dihydrogen phosphate (2A5NPDP) Journal of The Optical Society of America B-optical Physics. ,vol. 9, pp. 534- 547 ,(1992) , 10.1364/JOSAB.9.000534