Interaction of water vapor with gamma-radiation-induced defects in proton conductive polymers
作者： B. Tsuchiya , Y. Konishi , S. Nagata , T. Shikama
DOI: 10.1016/J.SSI.2008.12.030
关键词:
摘要: Abstract The correlation between protonic conduction and the amount of radiation-induced defects in gamma-ray-irradiated perfluorosulfonic acid (PFSA) polymers (Aciplex-SF-1004 ® ) has been investigated using a direct-current resistance method, transmission spectroscopy for ultraviolet (UV) visible (Vis) wavelength ranges Fourier transform infrared (FTIR) with attenuated total refraction (ATR) technique. proton conductivity polymers, which are irradiated dose up to 532 kGy under vacuum at room temperature subsequently exposure air, is enhanced by approximately three orders magnitude as compared that unirradiated polymer. UV–Vis spectra reveal presence fluorocarbon radicals, increase irradiation dose. It also observed FTIR peroxy free unsaturated species (COF), carboxyl group (COOH) containing carbon-oxygen double bond formed reactions radicals oxygen or water vapor air. In addition, an hydrogen concentration near-surface regions elastic recoil detection (ERD) production charge carriers such protons oxonium ions (H 3 O + interaction activating-radiation-induced leads enhancement conductivity.
elsevier.com
sci-hub.se 参考文章(11)
Mohamed Mahmoud Nasef, Hamdani Saidi, Khairul Zaman M. Dahlan, Electron beam irradiation effects on ethylene-tetrafluoroethylene copolymer films Radiation Physics and Chemistry. ,vol. 68, pp. 875- 883 ,(2003) , 10.1016/S0969-806X(03)00209-3
Klaus Lunkwitz, Uwe Lappan, Ulrich Scheler, Modification of perfluorinated polymers by high-energy irradiation Journal of Fluorine Chemistry. ,vol. 125, pp. 863- 873 ,(2004) , 10.1016/J.JFLUCHEM.2004.01.020
Alain Gruger, André Régis, Tatiana Schmatko, Philippe Colomban, Nanostructure of Nafion® membranes at different states of hydration Vibrational Spectroscopy. ,vol. 26, pp. 215- 225 ,(2001) , 10.1016/S0924-2031(01)00116-3
D. Fischer, U. Lappan, I. Hopfe, K.-J. Eichhorn, K. Lunkwitz, FTi.r. spectroscopy on electron irradiated polytetrafluoroethylene Polymer. ,vol. 39, pp. 573- 582 ,(1998) , 10.1016/S0032-3861(97)00304-2
Selma H Almeida, Yoshio Kawano, Effects of X-ray radiation on Nafion membrane Polymer Degradation and Stability. ,vol. 62, pp. 291- 297 ,(1998) , 10.1016/S0141-3910(98)00010-X
M.M Senna, H.A Aly, Z.I Ali, A.M El-Naggar, Structure-property behaviour of electron beam irradiated polytetrafluoroethylene and polytetrafluoroethylene-co-hexafluoropropylene Polymer Degradation and Stability. ,vol. 71, pp. 53- 60 ,(2000) , 10.1016/S0141-3910(00)00150-6
B. Tsuchiya, S. Nagata, K. Toh, T. Shikama, Measurement of the transport of hydrogen isotopes near the surface of metal-hydride and deuteride using elastic recoil detection technique Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 249, pp. 370- 373 ,(2006) , 10.1016/J.NIMB.2006.04.031
Zhenxing Liang, Weimin Chen, Jianguo Liu, Suli Wang, Zhenhua Zhou, Wenzhen Li, Gongquan Sun, Qin Xin, None, FT-IR study of the microstructure of Nafion ® membrane Journal of Membrane Science. ,vol. 233, pp. 39- 44 ,(2004) , 10.1016/J.MEMSCI.2003.12.008
C. Folonari, G. Iemmi, F. Manfredi, A. Rolle, Metal hydride fuel cells: A feasibility study and perspectives for vehicular applications Journal of The Less Common Metals. ,vol. 74, pp. 371- 378 ,(1980) , 10.1016/0022-5088(80)90175-7
M Ludvigsson, J Lindgren, J Tegenfeldt, FTIR study of water in cast Nafion films Electrochimica Acta. ,vol. 45, pp. 2267- 2271 ,(2000) , 10.1016/S0013-4686(99)00438-7