Two lightly stabilized decacarbonyltriosmium complexes

作者: Mamoru Tachikawa , John R. Shapley

DOI: 10.1016/S0022-328X(00)90975-6

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摘要: Abstract In cyclooctene solution H 2 Os 3 (CO) l0 reacts with ethylene to form 10 (C 8 14 ) , which can be transformed (NCCH . These two labile complexes are useful intermediates for preparation of decacarbonyltriosmium derivatives.

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