Photoorganocatalysis. What for
作者： Davide Ravelli , Maurizio Fagnoni , Angelo Albini
DOI: 10.1039/C2CS35250H
关键词:
摘要: In the reactions reviewed, an organic molecule under irradiation catalyzes a chemical reaction. The activation is based either on hydrogen or electron transfer. Commonly used photoorganocatalysts are aromatic ketones, quinones, heterocycles, dyes; intermediates formed radicals, radical ions and from precursors such as alkanes, alkenes, amines, ethers etc. Oxidation (mainly oxygenation) reduction processes obtained along with α-functionalization of amines conjugate additions, cycloadditions key characteristic method smooth generation highly reactive mild conditions.
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