Formation of Mach angle profiles during wet etching of silica and silicon nitride materials

作者: M. Ghulinyan , M. Bernard , R. Bartali , G. Pucker

DOI: 10.1016/J.APSUSC.2015.10.114

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摘要: Abstract In integrated circuit technology peeling of masking photoresist films is a major drawback during the long-timed wet etching materials. It causes an undesired film underetching, which often accompanied by formation complex etch profiles. Here we report on detailed study wedge-shaped profile in series silicon oxide, oxynitride and nitride materials buffered hydrofluoric acid (BHF) solution. The shape etched profiles reflects time-dependent adhesion properties to particular material can be perfectly circular, purely linear or combination both, separated knee feature. Starting from formal analogy between sonic boom propagation underetching process, model wedge mechanism analytically. This predicts final form as function time fits experimental data perfectly. We discuss how this knowledge extended design realization optical components such highly efficient etch-less vertical tapers for passive photonics.

参考文章(28)
Hiroshi Yanazawa, Adhesion model and experimental verification for polymer—SiO2 system Colloids and Surfaces. ,vol. 9, pp. 133- 145 ,(1984) , 10.1016/0166-6622(84)80153-5
Daniel Kolacyak, Jörg Ihde, Christian Merten, Andreas Hartwig, Uwe Lommatzsch, Fast functionalization of multi-walled carbon nanotubes by an atmospheric pressure plasma jet. Journal of Colloid and Interface Science. ,vol. 359, pp. 311- 317 ,(2011) , 10.1016/J.JCIS.2011.03.069
Kevin K. Lee, Desmond R. Lim, Lionel C. Kimerling, Jangho Shin, Franco Cerrina, Fabrication of ultralow-loss Si/SiO(2) waveguides by roughness reduction. Optics Letters. ,vol. 26, pp. 1888- 1890 ,(2001) , 10.1364/OL.26.001888
J Bühler, F-P Steiner, H Baltes, Silicon dioxide sacrificial layer etching in surface micromachining Journal of Micromechanics and Microengineering. ,vol. 7, pp. R1- R13 ,(1997) , 10.1088/0960-1317/7/1/001
B. Han, E. Rigo, R. Guider, S. Larcheri, G. Nunzi Conti, M. R. Vanacharla, A Chiasera, M. Ferrari, L. Pavesi, G. Pucker, G. C. Righini, M. Ghulinyan, Development and optical characterization of vertical tapers in SiON waveguides using gray-scale lithography Integrated Photonics: Materials, Devices, and Applications. ,vol. 8069, ,(2011) , 10.1117/12.886820
Hansuek Lee, Tong Chen, Jiang Li, Ki Youl Yang, Seokmin Jeon, Oskar Painter, Kerry J. Vahala, Chemically etched ultrahigh-Q wedge-resonator on a silicon chip Nature Photonics. ,vol. 6, pp. 369- 373 ,(2012) , 10.1038/NPHOTON.2012.109
K.R. Williams, R.S. Muller, Etch rates for micromachining processing IEEE\/ASME Journal of Microelectromechanical Systems. ,vol. 5, pp. 256- 269 ,(1996) , 10.1109/84.546406
M. Lipson, Guiding, modulating, and emitting light on Silicon-challenges and opportunities Journal of Lightwave Technology. ,vol. 23, pp. 4222- 4238 ,(2005) , 10.1109/JLT.2005.858225