Methylene-Linked Bis-NHC Half-Sandwich Ruthenium Complexes: Binding of Small Molecules and Catalysis toward Ketone Transfer Hydrogenation
作者： José Manuel Botubol-Ares , Safa Cordón-Ouahhabi , Zakaria Moutaoukil , Isidro G Collado , Manuel Jiménez-Tenorio
DOI: 10.1021/ACS.ORGANOMET.1C00045
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摘要: The complex [Cp*RuCl(COD)] reacts with LH2Cl2 (L = bis(3-methylimidazol-2-ylidene)) and LiBun in tetrahydrofuran at 65 °C furnishing the bis-carbene derivative [Cp*RuCl(L)] (2). This compound react...
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