XPS Study on the Charge Distribution in Chromium(0) Complexes

作者: Fumio Kinomura , Tadashi Tamura , Iwao Watanabe , Yu Yokoyama , Shigero Ikeda

DOI: 10.1246/BCSJ.49.3544

关键词:

摘要: Binding energies of core electrons in Cr(C6H6)2, Cr(C6H6)(CO)3, and Cr(CO)6 were measured by means X-ray photoelectron spectroscopic method solid phase. By comparison with their UPS spectra observed gasous phase, binding referred to vacuum level can be obtained. On the basis this result, charge distribution these complexes are estimated. The intramolecular relaxation energy Cr(C6H6)2 is also discussed.

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