Titania-Loaded Coal Char as Catalyst in Oxidation of Styrene with Aqueous Hydrogen Peroxide

作者: Mukhamad Nurhadi , Sheela Chandren , Lai Sin Yuan , Chin Siong Ho , Teuku Meurah Indra Mahlia

DOI: 10.1515/IJCRE-2016-0088

关键词:

摘要: Titania-loaded coal char catalyst was successfully prepared. The preparation steps involved pyrolysis of low rank at different temperatures and durations, sulfonation, impregnation titanium(IV) isopropoxide, then heating 110°C. It is found that the chars' surfaces were rough after sulfonation impregnation, while large pore volume, high surface area carbon composition observed temperature for short duration. These properties contributed to selectivity towards benzaldehyde (> 90%) 600°C (0.5-2 h)) in styrene oxidation using aqueous hydrogen peroxide as oxidant.

参考文章(26)
Charles N. Satterfield, Heterogeneous catalysis in practice McGraw-Hill. ,(1980)
Wangcheng Zhan, Yanglong Guo, Yanqin Wang, Yun Guo, Xiaohui Liu, Yunsong Wang, Zhigang Zhang, Guanzhong Lu, Study of Higher Selectivity to Styrene Oxide in the Epoxidation of Styrene with Hydrogen Peroxide over La-Doped MCM-48 Catalyst Journal of Physical Chemistry C. ,vol. 113, pp. 7181- 7185 ,(2009) , 10.1021/JP8101095
Hadi Nur, Modification of titanium surface species of titania by attachment of silica nanoparticles Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 133, pp. 49- 54 ,(2006) , 10.1016/J.MSEB.2006.05.003
Ya Liu, Jun Chen, Jianfeng Yao, Yong Lu, Lixiong Zhang, Xiaoqin Liu, Preparation and properties of sulfonated carbon-silica composites from sucrose dispersed on MCM-48 Chemical Engineering Journal. ,vol. 148, pp. 201- 206 ,(2009) , 10.1016/J.CEJ.2009.01.010
M.A Uguina, D.P Serrano, R Sanz, J.L.G Fierro, M López-Granados, R Mariscal, Preliminary study on the TS-1 deactivation during styrene oxidation with H2O2 Catalysis Today. ,vol. 61, pp. 263- 270 ,(2000) , 10.1016/S0920-5861(00)00381-3
Arindam Modak, Mahasweta Nandi, Asim Bhaumik, Titanium containing periodic mesoporous organosilica as an efficient catalyst for the epoxidation of alkenes Catalysis Today. ,vol. 198, pp. 45- 51 ,(2012) , 10.1016/J.CATTOD.2012.03.074
M. Ramakrishna Prasad, Mohamed S. Hamdy, Guido Mul, Elisabeth Bouwman, Eite Drent, Efficient catalytic epoxidation of olefins with silylated Ti-TUD-1 catalysts Journal of Catalysis. ,vol. 260, pp. 288- 294 ,(2008) , 10.1016/J.JCAT.2008.09.021
Jianqin Zhuang, Ding Ma, Zhimin Yan, Xiumei Liu, Xiuwen Han, Xinhe Bao, Yihua Zhang, Xinwen Guo, Xiangsheng Wang, Effect of acidity in TS-1 zeolites on product distribution of the styrene oxidation reaction Applied Catalysis A-general. ,vol. 258, pp. 1- 6 ,(2004) , 10.1016/J.APCATA.2003.06.002