Synthesis of amine‐modified solid Fe‐Zr adsorbents for CO2 adsorption
作者： Fan-Ming Yang , Ying Liu , Lang Chen , Chak-Tong Au , Shuang-Feng Yin
DOI: 10.1002/JCTB.4827
关键词:
摘要: BACKGROUND With the aggravation of greenhouse effect, much attention is given to capture CO2 before its emission into atmosphere. So far, various solid adsorbents have been developed and used. Among them, materials modified with organic-amines are promising on account good adsorption desorption performance. In present work, triethylenetetramine (TETA) Fe-Zr were synthesized characterized. The performance for was tested in a stream 5% CO2. RESULTS The support first synthesized, TETA successfully grafted onto surface. show thermal stability ability. Increase amount increased gas flow rate positive influence whereas increase temperature has negative effect capacity. At 200 mg loading 20 cm3 g−1, adsorbent achieves maximum capacity 4.1 mmol g−1 at 75 °C. addition, exhibits excellent reusability cyclic performance. CONCLUSION Remarkable recyclability suggest that TETA-functionalized high potential industry. © 2015 Society Chemical Industry
sci-hub.se 参考文章(51)
Joel K. J. Yong, Geoff W. Stevens, Frank Caruso, Sandra E. Kentish, The use of carbonic anhydrase to accelerate carbon dioxide capture processes Journal of Chemical Technology & Biotechnology. ,vol. 90, pp. 3- 10 ,(2015) , 10.1002/JCTB.4502
Esmail R Monazam, Lawrence J Shadle, David C Miller, Henry W Pennline, Daniel J Fauth, James S Hoffman, McMahan L Gray, None, Equilibrium and kinetics analysis of carbon dioxide capture using immobilized amine on a mesoporous silica Aiche Journal. ,vol. 59, pp. 923- 935 ,(2013) , 10.1002/AIC.13870
Xia Wang, Qingjie Guo, Jun Zhao, Linlin Chen, Mixed amine-modified MCM-41 sorbents for CO2 capture International Journal of Greenhouse Gas Control. ,vol. 37, pp. 90- 98 ,(2015) , 10.1016/J.IJGGC.2015.03.018
Zhonghua Zhang, Xiaoliang Ma, Dongxiang Wang, Chunshan Song, Yonggang Wang, Development of silica‐gel‐supported polyethylenimine sorbents for CO2 capture from flue gas Aiche Journal. ,vol. 58, pp. 2495- 2502 ,(2012) , 10.1002/AIC.12771
S.-M. Hong, K. B. Lee, Solvent-assisted amine modification of graphite oxide for CO2 adsorption RSC Advances. ,vol. 4, pp. 56707- 56712 ,(2014) , 10.1039/C4RA09314C
Fateme Rezaei, Miles A. Sakwa-Novak, Sumit Bali, Daniel M. Duncanson, Christopher W. Jones, Shaping amine-based solid CO2 adsorbents: Effects of pelletization pressure on the physical and chemical properties Microporous and Mesoporous Materials. ,vol. 204, pp. 34- 42 ,(2015) , 10.1016/J.MICROMESO.2014.10.047
Jian Lü, Cristina Perez-Krap, Mikhail Suyetin, Nada H Alsmail, Yong Yan, Sihai Yang, William Lewis, Elena Bichoutskaia, Chiu C Tang, Alexander J Blake, Rong Cao, Martin Schröder, None, A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity Journal of the American Chemical Society. ,vol. 136, pp. 12828- 12831 ,(2014) , 10.1021/JA506577G
A. Olea, E. S. Sanz-Pérez, A. Arencibia, R. Sanz, G. Calleja, Amino-functionalized pore-expanded SBA-15 for CO2 adsorption Adsorption. ,vol. 19, pp. 589- 600 ,(2013) , 10.1007/S10450-013-9482-Y
Youlong Zhu, Wei Zhang, Reversible tuning of pore size and CO2 adsorption in azobenzene functionalized porous organic polymers Chemical Science. ,vol. 5, pp. 4957- 4961 ,(2014) , 10.1039/C4SC02305F
Jason J. Ge, Dong Zhang, Qing Li, Haoqing Hou, Matthew J. Graham, Liming Dai, Frank W. Harris, Stephen Z. D. Cheng, Multiwalled Carbon Nanotubes with Chemically Grafted Polyetherimides Journal of the American Chemical Society. ,vol. 127, pp. 9984- 9985 ,(2005) , 10.1021/JA050924S