Enhancement of mechanical and thermal properties of Poplar through the treatment of glyoxal-urea/nano-SiO2

作者: Yutao Yan , Youming Dong , Jianzhang Li , Shifeng Zhang , Changlei Xia

DOI: 10.1039/C5RA07294H

关键词:

摘要: Glyoxal is a cross-linking agent that could effectively improve dimensional stability and water resistance with compromising the mechanical properties of wood materials. This study explores relevant disadvantages glyoxal-treated wood, in an effort to overcome drawbacks, environmental-friendly glyoxal-urea (GU) resin synthesized from urea glyoxal, combined nano-SiO2 treat Poplar wood. Results showed GU resin-treated were significantly increased compared those treated glyoxal alone, incorporation further improved performance. The fracture morphology GU/nano-SiO2-treated was also characterized, indicating elasticity. Scanning electron microscopy energy dispersive X-ray (SEM-EDX) results existed not only cell lumens, but walls. Fourier transform infrared spectroscopy (FT-IR) test formation into samples. Thermal analysis demonstrated thermal after samples solely glyoxal-treated. Improvement can most likely be attributed cross-linkage length among celluloses, and/or filling effect GU/SiO2 voids

参考文章(42)
Yanjun Xie, Qiliang Fu, Qingwen Wang, Zefang Xiao, Holger Militz, Effects of chemical modification on the mechanical properties of wood European Journal of Wood and Wood Products. ,vol. 71, pp. 401- 416 ,(2013) , 10.1007/S00107-013-0693-4
R. Yasuda, K. Minato, Misato Norimoto, Chemical modification of wood by non-formaldehyde cross-linking reagents Wood Science and Technology. ,vol. 28, pp. 209- 218 ,(1994) , 10.1007/BF00193329
Jinshu Shi, Jianzhang Li, Wenrui Zhou, Derong Zhang, Improvement of wood properties by urea-formaldehyde resin and nano-SiO2 Frontiers of Forestry in China. ,vol. 2, pp. 104- 109 ,(2007) , 10.1007/S11461-007-0017-0
Hao-Jie Song, Zhao-Zhu Zhang, Xue-Hu Men, The tribological behaviors of the polyurethane coating filled with nano-SiO2 under different lubrication conditions Composites Part A: Applied Science and Manufacturing. ,vol. 39, pp. 188- 194 ,(2008) , 10.1016/J.COMPOSITESA.2007.11.003
Chris P. Gabrielli, Frederick A. Kamke, Phenol–formaldehyde impregnation of densified wood for improved dimensional stability Wood Science and Technology. ,vol. 44, pp. 95- 104 ,(2010) , 10.1007/S00226-009-0253-6
Wenjun Zou, Jin Peng, Yun Yang, Linqi Zhang, Bo Liao, Furen Xiao, Effect of nano-SiO2 on the performance of poly(MMA/BA/MAA)/EP Materials Letters. ,vol. 61, pp. 725- 729 ,(2007) , 10.1016/J.MATLET.2006.05.073
Alfred J. Crosby, Jong‐Young Lee, Polymer Nanocomposites: The “Nano” Effect on Mechanical Properties Polymer Reviews. ,vol. 47, pp. 217- 229 ,(2007) , 10.1080/15583720701271278
Rashmi Rekha Devi, Tarun K. Maji, Effect of nano-SiO2 on properties of wood/polymer/clay nanocomposites Wood Science and Technology. ,vol. 46, pp. 1151- 1168 ,(2012) , 10.1007/S00226-012-0471-1
T. Nakano, Reaction of glyoxal and glyoxal/glycol with wood Wood Science and Technology. ,vol. 28, pp. 23- 33 ,(1993) , 10.1007/BF00193873
Jian-Zhang Li, Takeshi Furuno, Wen-Rui Zhou, Qian Ren, Xiu-Zhi Han, Jin-Ping Zhao, Properties of Acetylated Wood Prepared at Low Temperature in the Presence of Catalysts Journal of Wood Chemistry and Technology. ,vol. 29, pp. 241- 250 ,(2009) , 10.1080/02773810903009499