Enhanced CO2 adsorptive performance of PEI/SBA-15 adsorbent using phosphate ester based surfactants as additives
作者： Dandan Cheng , Yue Liu , Haiqiang Wang , Xiaole Weng , Zhongbiao Wu
DOI: 10.1016/J.JES.2015.04.025
关键词:
摘要: In this study, a series of polyetherimide/SBA-15: 2-D hexagonal P6mm, Santa Barbara USA (PEI/SBA-15) adsorbents modified by phosphoric ester based surfactants (including tri(2-ethylhexyl) phosphate (TEP), bis(2-ethylhexyl) (BEP) and trimethyl phosphonoacetate (TMPA)) were prepared for CO2 adsorption. Experimental results indicated that the addition TEP BEP had positive effects on adsorption capacity over PEI/SBA-15. particular, amount could be improved around 20% 45PEI-5TEP/SBA-15 compared to additive-free adsorbent. This attributed decrease diffusion resistance in PEI bulk network due interactions between loaded molecules, which was further confirmed kinetics results. addition, it also found cyclic performance TEP-modified adsorbent better than surfactant-free one. two main reasons, situ DRIFT TG-DSC tests. First more importantly, adsorbed species desorbed rapidly during thermal desorption process. Furthermore, enhanced stability after ensured lower degradation amine groups adsorption/desorption cycles.
jesc.ac.cn
elsevier.com参考文章(51)
Martin Cinke, Jing Li, Charles W. Bauschlicher, Alessandra Ricca, M. Meyyappan, CO2 adsorption in single-walled carbon nanotubes Chemical Physics Letters. ,vol. 376, pp. 761- 766 ,(2003) , 10.1016/S0009-2614(03)01124-2
Peter J.E. Harlick, F. Handan Tezel, An experimental adsorbent screening study for CO2 removal from N2 Microporous and Mesoporous Materials. ,vol. 76, pp. 71- 79 ,(2004) , 10.1016/J.MICROMESO.2004.07.035
Praveen Bollini, Stephanie A. Didas, Christopher W. Jones, Amine-oxide hybrid materials for acid gas separations Journal of Materials Chemistry. ,vol. 21, pp. 15100- 15120 ,(2011) , 10.1039/C1JM12522B
Stephen R. Caskey, Antek G. Wong-Foy, Adam J. Matzger, Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores. Journal of the American Chemical Society. ,vol. 130, pp. 10870- 10871 ,(2008) , 10.1021/JA8036096
Zhenhe Chen, Shubo Deng, Haoran Wei, Bin Wang, Jun Huang, Gang Yu, Polyethylenimine-Impregnated Resin for High CO2 Adsorption: An Efficient Adsorbent for CO2 Capture from Simulated Flue Gas and Ambient Air ACS Applied Materials & Interfaces. ,vol. 5, pp. 6937- 6945 ,(2013) , 10.1021/AM400661B
Jitong Wang, Donghui Long, Huanhuan Zhou, Qingjun Chen, Xiaojun Liu, Licheng Ling, Surfactant promoted solid amine sorbents for CO2 capture Energy and Environmental Science. ,vol. 5, pp. 5742- 5749 ,(2012) , 10.1039/C2EE02272A
Zoltán Bacsik, Nanna Ahlsten, Asraa Ziadi, Guoying Zhao, Alfonso E. Garcia-Bennett, Belén Martín-Matute, Niklas Hedin, Mechanisms and Kinetics for Sorption of CO2 on Bicontinuous Mesoporous Silica Modified with n-Propylamine Langmuir. ,vol. 27, pp. 11118- 11128 ,(2011) , 10.1021/LA202033P
Xiaochun Xu, Chunshan Song, John M. Andresen, Bruce G. Miller, Alan W. Scaroni, Novel Polyethylenimine-Modified Mesoporous Molecular Sieve of MCM-41 Type as High-Capacity Adsorbent for CO2 Capture Energy & Fuels. ,vol. 16, pp. 1463- 1469 ,(2002) , 10.1021/EF020058U
Genggeng Qi, Yanbing Wang, Luis Estevez, Xiaonan Duan, Nkechi Anako, Ah-Hyung Alissa Park, Wen Li, Christopher W. Jones, Emmanuel P. Giannelis, High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules Energy and Environmental Science. ,vol. 4, pp. 444- 452 ,(2011) , 10.1039/C0EE00213E
Jie Liu, Dandan Cheng, Yue Liu, Zhongbiao Wu, Adsorptive Removal of Carbon Dioxide Using Polyethyleneimine Supported on Propanesulfonic-Acid-Functionalized Mesoporous SBA-15 Energy & Fuels. ,vol. 27, pp. 5416- 5422 ,(2013) , 10.1021/EF4011252