Copper(II) nanoparticles: an efficient and reusable catalyst in green oxidation of benzyl alcohols to benzaldehydes in water
作者： Razieh Mirsafaei , Majid M. Heravi , Tayebeh Hosseinnejad , Shervin Ahmadi
DOI: 10.1002/AOC.3509
关键词:
摘要: Copper(II) nanoparticles immobilized onto 3-aminopropyltriethoxysilane (APTES) supported on mesoporous silica KIT-5 nanocomposite (AK) was prepared. The APTES group manipulated as a suitable coordinating agent for copper(II) and fully characterized using FT-IR, SEM, EDX, ICP, TGA, XRD UV–visible methods. Moreover, quantitative description metal–ligand interactions in the APTES-KIT-5 silica-supported acetate complex assessed via quantum chemistry computations. This novel transition metal heterogeneous surface used an effective catalyst low loading selective oxidation of differently substituted benzylic alcohols water, H2O2 oxidant to give corresponding carbonyl compounds high excellent yields. nanocatalyst can be recovered reused several times without any significant loss activity. Copyright © 2016 John Wiley & Sons, Ltd.
sci-hub.se 参考文章(53)
Makoto Misono, Chapter 1 - Basis of Heterogeneous Catalysis Studies in Surface Science and Catalysis. ,vol. 176, pp. 1- 23 ,(2013) , 10.1016/B978-0-444-53833-8.00001-6
Amir Reza Judy Azar, Elham Safaei, Sajjad Mohebbi, A novel Schiff base of Mn(III) complex supported on magnetic cobalt nanoparticles as a highly efficient retrievable heterogeneous catalyst in oxidation of alcohols and sulfides compounds Materials Research Bulletin. ,vol. 70, pp. 753- 761 ,(2015) , 10.1016/J.MATERRESBULL.2015.05.016
A. Miller, R. Espanani, A. Junker, D. Hendry, N. Wilkinson, D. Bollinger, J.M. Abelleira-Pereira, M.A. Deshusses, E. Inniss, W. Jacoby, Supercritical water oxidation of a model fecal sludge without the use of a co-fuel Chemosphere. ,vol. 141, pp. 189- 196 ,(2015) , 10.1016/J.CHEMOSPHERE.2015.06.076
Hulin Zhang, Guang Yao, Liping Wang, Yuanjie Su, Weiqing Yang, Yuan Lin, 3D Pt/MoO 3 nanocatalysts fabricated for effective electrocatalytic oxidation of alcohol Applied Surface Science. ,vol. 356, pp. 294- 300 ,(2015) , 10.1016/J.APSUSC.2015.08.082
Houan Zhang, Jianxian Lv, Yihui Wu, Siyong Gu, Yu Huang, Ying Chen, Oxidation behavior of (Mo,W)Si2–Si3N4 composite coating on molybdenum substrate at 1600 °C Ceramics International. ,vol. 41, pp. 14890- 14895 ,(2015) , 10.1016/J.CERAMINT.2015.08.012
Paula M.A. Machado, Leonardo M. Lube, Marcione D.E. Tiradentes, Christiane Fernandes, Clícia A. Gomes, Alexandre M. Stumbo, Rosane A.S. San Gil, Lorenzo C. Visentin, Dalber R. Sanchez, Vera L.A. Frescura, Jessee S.A. Silva, Adolfo Horn, Synthesis, characterization and activity of homogeneous and heterogeneous (SiO2, NaY, MCM-41) iron(III) catalysts on cyclohexane and cyclohexene oxidation Applied Catalysis A: General. ,vol. 507, pp. 119- 129 ,(2015) , 10.1016/J.APCATA.2015.09.035
Paula Cruz, Yolanda Pérez, Isabel del Hierro, Mariano Fajardo, Copper, copper oxide nanoparticles and copper complexes supported on mesoporous SBA-15 as catalysts in the selective oxidation of benzyl alcohol in aqueous phase Microporous and Mesoporous Materials. ,vol. 220, pp. 136- 147 ,(2016) , 10.1016/J.MICROMESO.2015.08.029
Firouzeh Nemati, Majid M. Heravi, Ali Elhampour, Magnetic nano-Fe3O4@TiO2/Cu2O core–shell composite: an efficient novel catalyst for the regioselective synthesis of 1,2,3-triazoles using a click reaction RSC Advances. ,vol. 5, pp. 45775- 45784 ,(2015) , 10.1039/C5RA06810J
Qiang Zeng, Frank W. Lewis, Laurence M. Harwood, František Hartl, Role of ligands in catalytic water oxidation by mononuclear ruthenium complexes Coordination Chemistry Reviews. pp. 88- 101 ,(2015) , 10.1016/J.CCR.2015.03.003
Majid M. Heravi, Niloofar Tavakoli-Hoseini, Fatemeh F. Bamoharram, Silica-supported Preyssler nano particles: a green, reusable and highly efficient heterogeneous catalyst for the synthesis of carbamatoalkyl naphthols Green Chemistry Letters and Reviews. ,vol. 3, pp. 263- 267 ,(2010) , 10.1080/17518251003749387