Quantum effects in intramolecular energy transfer

作者: Eric J. Heller

DOI: 10.1016/0009-2614(79)80049-4

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摘要: Abstract Anharmonic potentials which are presumed to be classically quasi-ergodic, but have symmetries leading degenerate quantum states, fail in the case transfer energy equivalently among rigorously equivalent phase space locations. This is shown using simple group theory and illustrated for of Henon-Heiles potential

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