Laser-induced breakdown spectroscopy using mid-infrared femtosecond pulses

作者: K. C. Hartig , J. Colgan , D. P. Kilcrease , J. E. Barefield , I. Jovanovic

DOI: 10.1063/1.4927624

关键词:

摘要: We report on a laser-induced breakdown spectroscopy (LIBS) experiment driven by mid-infrared (2.05-μm) fs pulses, in which time-resolved emission spectra of copper were studied. Ab-initio modeling is consistent with the results new measurements at 2.05 μm and traditional 800-nm fs-LIBS. Ablation pulses plasma lower density temperature compared to fs-LIBS performed shorter laser wavelength. LIBS signal-to-background ratio ∼50% greater signal-to-noise ∼40% than near-infrared

参考文章(38)
N. Konjevic, M. S. Dimitrijevic, Simple formulae for estimating Stark widths and shifts of neutral atom lines Astronomy and Astrophysics. ,vol. 163, pp. 297- 300 ,(1986)
B Zmerli, N Ben Nessib, M S Dimitrijević, S Sahal-Bréchot, Stark broadening calculations of neutral copper spectral lines and temperature dependence Physica Scripta. ,vol. 82, pp. 055301- ,(2010) , 10.1088/0031-8949/82/05/055301
A. De Giacomo, M. Dell'Aglio, A. Santagata, R. Teghil, Early stage emission spectroscopy study of metallic titanium plasma induced in air by femtosecond- and nanosecond-laser pulses Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 60, pp. 935- 947 ,(2005) , 10.1016/J.SAB.2005.05.026
R. Fantoni, L. Caneve, F. Colao, L. Fornarini, V. Lazic, V. Spizzichino, Methodologies for laboratory Laser Induced Breakdown Spectroscopy semi-quantitative and quantitative analysis—A review ☆ Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 63, pp. 1097- 1108 ,(2008) , 10.1016/J.SAB.2008.08.008
John T. Schiffern, David W. Doerr, Dennis R. Alexander, Optimization of collinear double-pulse femtosecond laser-induced breakdown spectroscopy of silicon Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 62, pp. 1412- 1418 ,(2007) , 10.1016/J.SAB.2007.10.042
Sven Merk, Alexander Demidov, Daniel Shelby, Igor B. Gornushkin, Ulrich Panne, Ben W. Smith, Nicoló Omenetto, Diagnostic of Laser-Induced Plasma Using Abel Inversion and Radiation Modeling Applied Spectroscopy. ,vol. 67, pp. 851- 859 ,(2013) , 10.1366/12-06929
M A Hafez, M A Khedr, F F Elaksher, Y E Gamal, Characteristics of Cu plasma produced by a laser interaction with a solid target Plasma Sources Science and Technology. ,vol. 12, pp. 185- 198 ,(2003) , 10.1088/0963-0252/12/2/310
A. Santagata, R. Teghil, G. Albano, D. Spera, P. Villani, A. De Bonis, G.P. Parisi, A. Galasso, fs/ns dual-pulse LIBS analytic survey for copper-based alloys Applied Surface Science. ,vol. 254, pp. 863- 867 ,(2007) , 10.1016/J.APSUSC.2007.07.203
R. Gaudiuso, M. Dell'Aglio, O. De Pascale, A. Santagata, A. De Giacomo, Laser-induced plasma analysis of copper alloys based on Local Thermodynamic Equilibrium: An alternative approach to plasma temperature determination and archeometric applications Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 74, pp. 38- 45 ,(2012) , 10.1016/J.SAB.2012.06.034
Xueshi Bai, Qianli Ma, Maxime Perrier, Vincent Motto-Ros, David Sabourdy, Luc Nguyen, Alain Jalocha, Jin Yu, Experimental study of laser-induced plasma: Influence of laser fluence and pulse duration Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 87, pp. 27- 35 ,(2013) , 10.1016/J.SAB.2013.05.019