Estimation of Physical Properties

摘要: The article contains sections titled: 1. Introduction 1.1. Scope 1.2. Data Sources 1.3. Theoretical and Empirical Methods 2. Molecular Macroscopic Properties 2.1. Intermolecular Forces 2.2. Theorem of Corresponding States 2.3. Estimation Critical Properties 2.4. Other Characteristic Constants Pure Compounds 3. Thermal Caloric Properties Single-Phase Systems 3.1. Pressure - Volume Temperature Behavior Gases Liquids 3.1.1. Pure Gases 3.1.2. Pure Liquids 3.1.3. Mixtures 3.1.3.1. Gas Mixtures 3.1.3.2. Liquid Mixtures 3.2. Caloric Properties 3.2.1. Heat Capacity Ideal Gases 3.2.2. Heat Liquids 3.2.3. Heat Capacities Liquid Mixtures 4. Phase Equilibria 4.1. Pure Compounds 4.1.1. Vapor Pressure, Boiling Point, Melting Point 4.1.2. Enthalpy Vaporization 4.2. Mixtures 4.2.1. Vapor Equilibria with Liquid-Phase Activity Coefficients 4.2.1.1. Basic Considerations 4.2.1.2. Data Correlation: Binary Multicomponent Mixtures Nonelectrolytes 4.2.1.3. Prediction Equilibrium Data 4.2.2. Vapor Gas Equations State 4.2.2.1. Basic Considerations 4.2.2.2. Data Correlation 4.2.2.3. Prediction Vapor-Liquid Gas-Liquid Equilibria 4.2.3. Liquid Equilibria 4.2.4. Solid Equilibria 5. Thermodynamic Data Chemical Reactions 5.1. Definitions 5.1.1. Reaction Enthalpy 5.1.2. Gibbs Energy Reaction Equilibrium 5.2. Group Contribution Methods for the Estimation Enthalpies Gibbs Energies Formation 5.3. Applications 5.3.1. Reaction Enthalpy 5.3.2. Chemical Equilibrium 6. Transport Compounds Mixtures 6.1. Viscosity 6.1.1. Viscosity Gases 6.1.2. Viscosity Mixtures 6.1.3. Viscosity Liquids 6.1.4. Viscosity Mixtures 6.2. Thermal Conductivity 6.2.1. Thermal Conductivity at Low Pressure 6.2.2. Thermal High Pressure 6.2.3. Thermal Mixtures 6.2.4. Thermal Liquids 6.2.5. Thermal Mixtures 6.3. Diffusion Coefficients 6.3.1. Diffusion Coefficients Moderate Pressures 6.3.2. Diffusion Liquids 7. Surface Tension Liquids 7.1. Surface Liquids 7.2. Surface