The chemical modification seen in the Cu/ZnO methanol synthesis catalysts

作者: T. Fujitani , J. Nakamura

DOI: 10.1016/S0926-860X(99)00313-0

关键词:

摘要: … On the other hand, using in situ IRAS, we have found that the presence of Zn significantly promotes the hydrogenation process of formate to methoxy intermediates. Fig. 14 shows in situ …

参考文章(56)
T. Fujitani, T. Matsuda, Y. Kushida, S. Ogihara, T. Uchijima, J. Nakamura, Creation of the active site for methanol synthesis on a Cu/SiO2 catalyst Catalysis Letters. ,vol. 49, pp. 175- 179 ,(1997) , 10.1023/A:1019069708459
R.A. Hadden, B. Sakakini, J. Tabatabaei, K.C. Waugh, Adsorption and reaction induced morphological changes of the copper surface of a methanol synthesis catalyst Catalysis Letters. ,vol. 44, pp. 145- 151 ,(1997) , 10.1023/A:1018962016811
J. Nakamura, I. Nakamura, T. Uchijima, T. Watanabe, T. Fujitani, Model studies of methanol synthesis on copper catalysts Studies in Surface Science and Catalysis. ,vol. 101, pp. 1389- 1399 ,(1996) , 10.1016/S0167-2991(96)80351-X
T. Fujitani, J. Nakamura, The effect of ZnO in methanol synthesis catalysts on Cu dispersion and the specific activity Catalysis Letters. ,vol. 56, pp. 119- 124 ,(1998) , 10.1023/A:1019000927366
M Bowker, RA Hadden, H Houghton, JNK Hyland, KC Waugh, The mechanism of methanol synthesis on copper/zinc oxide/alumina catalysts Journal of Catalysis. ,vol. 109, pp. 263- 273 ,(1988) , 10.1016/0021-9517(88)90209-6
T. Fujitani, M. Saito, Y. Kanai, T. Kakumoto, T. Watanabe, J. Nakamura, T. Uchijima, The role of metal oxides in promoting a copper catalyst for methanol synthesis Catalysis Letters. ,vol. 25, pp. 271- 276 ,(1994) , 10.1007/BF00816307
Charles T. Campbell, Karen A. Daube, J.M. White, Cu/ZnO(0001̄) and ZnOx/Cu(111): Model catalysts for methanol synthesis Surface Science. ,vol. 182, pp. 458- 476 ,(1987) , 10.1016/0039-6028(87)90013-6