Synthese de coordinats macrocycliques polyazotes comportant une fonction amine secondaire discriminee
作者： J.F. Pilichowski , J.M. Lehn , J.P. Sauvage , J.C. Gramain
DOI: 10.1016/S0040-4020(01)96560-3
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摘要: Resume On decrit le schema de synthese deux polyazamacrocycles comportant un atome d'azote discrimine par rapport aux autres la:(tri-N-methyl)-tetraaza-1,4,7,10-cyclododecane et la (tetra-N-methyl)-pentaaza-1,4,7,10,13-cyclopentadecane ont ainsi ete preparees. Le seul secondaire present dans ces molecules est susceptible reagir des reactions d'alkylation d'acylation, conduire a nouveaux ligands polyazotes macrocycliques porteurs fonctionnalites laterales. Plusieurs complexes metallques entre les metaux transition (Cu, Co, Ni, Rh) sont egalement decrits
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