Synthesis, characterisation and catalytic activity of cadmium cobaltite nanoparticles: part 87
作者： Supriya Singh , Pratibha Srivastava , Inderpal Singh Kapoor , Gurdip Singh
DOI: 10.1080/17458080.2013.788225
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摘要: In this paper, we report the synthesis of cadmium cobaltite nanoparticles (CCNs) and their characterisation by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) transmission (TEM). The particles are spherical in shape average particle size is order 20–30 nm. Its catalytic activity was investigated through thermal decomposition ammonium perchlorate (AP), composite solid propellants (CSPs), 5-nitro-2,4-dihydro-3H-1,2,4-triazole-3-one (NTO) 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX) using thermogravimetry (TG), TG coupled with differential calorimetry (TG-DSC) ignition delay measurements. kinetics AP + CCNs has also been isoconversional model-fitting approaches, which have applied to data for isothermal decomposition. burning rate CSPs considerably enhanced these nanoparticles. delays activation energies found...
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sci-hub.se 参考文章(42)
Gurdip Singh, S Prem Felix, Studies on energetic compounds 25. An overview of preparation, thermolysis and applications of the salts of 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) Journal of Hazardous Materials. ,vol. 90, pp. 1- 17 ,(2002) , 10.1016/S0304-3894(01)00349-1
RP Rastogi, Gurdip Singh, BL Dubey, CS Shukla, Solid state chemistry of copper chromite used as a catalyst for the burning of ammonium perchlorate/polystyrene propellants Journal of Catalysis. ,vol. 65, pp. 25- 30 ,(1980) , 10.1016/0021-9517(80)90274-2
G. Singh, R. R. Singh, A. P. Rai, I. P. S. Kapoor, Thermal analysis of ammonium perchlorate +polystyrene +additive mixtures I Journal of Thermal Analysis. ,vol. 36, pp. 2539- 2546 ,(1990) , 10.1007/BF01913651
Gurdip Singh, S.Prem Felix, Studies of energetic compounds, part 29: effect of NTO and its salts on the combustion and condensed phase thermolysis of composite solid propellants, HTPB-AP Combustion and Flame. ,vol. 132, pp. 422- 432 ,(2003) , 10.1016/S0010-2180(02)00479-0
L. S. Birks, H. Friedman, Particle Size Determination from X‐Ray Line Broadening Journal of Applied Physics. ,vol. 17, pp. 687- 692 ,(1946) , 10.1063/1.1707771
Richard. Behrens, Thermal decomposition of energetic materials: temporal behaviors of the rates of formation of the gaseous pyrolysis products from condensed-phase decomposition of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine The Journal of Physical Chemistry. ,vol. 94, pp. 6706- 6718 ,(1990) , 10.1021/J100380A034
M. A. Peña, J. L. G. Fierro, Chemical structures and performance of perovskite oxides. Chemical Reviews. ,vol. 101, pp. 1981- 2017 ,(2001) , 10.1021/CR980129F
P.E. Gongwer, T.B. Brill, Thermal decomposition of energetic materials 73: the identity and temperature dependence of “minor” products from flash-heated RDX Combustion and Flame. ,vol. 115, pp. 417- 423 ,(1998) , 10.1016/S0010-2180(98)00011-X
Jun Yang, Jian Bao Li, Hong Lin, Xiao Zhan Yang, Ning Wang, Xu Guang Tong, Synthesis and Characterization of Regular Hexagonal NiCo2O4 Nanosheets Key Engineering Materials. ,vol. 336-338, pp. 2027- 2029 ,(2007) , 10.4028/WWW.SCIENTIFIC.NET/KEM.336-338.2027
Gurdip Singh, S.Prem Felix, Studies on energetic compounds. Part 32: crystal structure, thermolysis and applications of NTO and its salts Journal of Molecular Structure. ,vol. 649, pp. 71- 83 ,(2003) , 10.1016/S0022-2860(02)00717-2