Effect of polystyrene on poly(ethylene terephthalate) crystallization

作者: Renate Maria Ramos Wellen

DOI: 10.1590/1516-1439.302614

关键词:

摘要: Blends of poly(ethylene terephthalate) (PET) and polystyrene (PS) with PS content ranging from 0% to 60% by weight, were compounded in a laboratory internal mixer, followed quenching into iced water, resulting substantially amorphous compounds. Blend morphology was analyzed scanning electron microscopy (SEM). Standard differential calorimetry (DSC) used study the cold crystallization melting behavior PET PET/PS blends. SEM micrographs show two-phase structure made up spherical particles dispersed matrix. DSC scans showed that is affected heating rate addition even small amounts PS. In particular, significantly reduced incorporation 1% PS, attributed anti-nucleating effect on PET. The amount crystallized characteristics (temperature, rate) are not either or rate.

参考文章(46)
Stoyko Fakirov, Ilija Seganov, Ewgenija Kurdowa, Effect of chain composition of poly(ethylene terephthalate) structure and properties Macromolecular Chemistry and Physics. ,vol. 182, pp. 185- 197 ,(1981) , 10.1002/MACP.1981.021820120
Renate M. R. Wellen, Marcelo S. Rabello, Antinucleating action of polystyrene on the isothermal cold crystallization of poly(ethylene terephthalate) Journal of Applied Polymer Science. ,vol. 114, pp. 1884- 1895 ,(2009) , 10.1002/APP.29569
Woo Nyon Kim, Charles M. Burns, Phase behavior of blends of polycarbonate with partially miscible polymers Journal of Applied Polymer Science. ,vol. 41, pp. 1575- 1593 ,(1990) , 10.1002/APP.1990.070410718
Renate M.R. Wellen, Eduardo Canedo, Marcelo S. Rabello, Nonisothermal cold crystallization of poly(ethylene terephthalate) Journal of Materials Research. ,vol. 26, pp. 1107- 1115 ,(2011) , 10.1557/JMR.2011.44
T. K. Kwei, H. L. Frisch, Interaction Parameter in Polymer Mixtures Macromolecules. ,vol. 11, pp. 1267- 1271 ,(1978) , 10.1021/MA60066A039
Shaul M. Aharoni, Nucleation of PET crystallization by metal hydroxides Journal of Applied Polymer Science. ,vol. 29, pp. 853- 865 ,(1984) , 10.1002/APP.1984.070290314
V. M. Nadkarni, V. L. Shingankuli, J. P. Jog, Effect of blending on the crystallization behavior of PET Journal of Applied Polymer Science. ,vol. 46, pp. 339- 351 ,(1992) , 10.1002/APP.1992.070460215