Two Distinct Supramolecular Motifs from Bis(2-methylimidazo-1-yl) Methane: An Infinite [n]Catenane and A Discrete M6 Metal-Organic Framework
作者： Chuan-Ming Jin , Ling-Yan Wu , Huang Lu , Yan Xu
DOI: 10.1021/CG070143Y
关键词:
摘要: Two distinct supramolecular motifs, [Ag4(2-mBIM)4(BF4)4H2O]n (1) and [Ag6(2-mBIM)6(SO3CF3)6]n (2), were self-assembled from the ligand bis(2-methylimidazo-1-yl) methane (2-mBIM) AgBF4 or AgSO3CF3. Their structure was characterized by elemental analyses, IR spectroscopy single-crystal X-ray diffraction. Compound 1 is a 1D infinite [n]catenane molecule, compound 2 discrete M6 metal−organic framework with chair conformation like that of cyclohexane.
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sci-hub.se 参考文章(38)
Jean‐Marie Lehn, Supramolecular Chemistry: Concepts and Perspectives Malta II : Frontiers of Chemical Sciences 2 : Research and Education in the Middle East, Malta. ,(1995) , 10.1002/3527607439
Michito Yoshizawa, Muneki Nagao, Kazuhiko Umemoto, Kumar Biradha, Makoto Fujita, Shigeru Sakamoto, Kentaro Yamaguchi, Side chain-directed assembly of triangular molecular panels into a tetrahedron vs. open cone. Chemical Communications. pp. 1808- 1809 ,(2003) , 10.1039/B305129C
Stefan Leininger, Bogdan Olenyuk, Peter J. Stang, Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals Chemical Reviews. ,vol. 100, pp. 853- 908 ,(2000) , 10.1021/CR9601324
Jean-Claude G. Bünzli, Claude Piguet, Lanthanide-containing molecular and supramolecular polymetallic functional assemblies. Chemical Reviews. ,vol. 102, pp. 1897- 1928 ,(2002) , 10.1021/CR010299J
Ming-Liang Tong, Bao-Hui Ye, Ji-Wen Cai, Xiao-Ming Chen, Seik Weng Ng, None, Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(2).(2,4'-bpy)(2).H(2)O and [Cu(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(4).(4,4'-H(2)Bpy) (M = Cd(II), Zn(II) and bpy = Bipyridine). Inorganic Chemistry. ,vol. 37, pp. 2645- 2650 ,(1998) , 10.1021/IC9714293
Brian Moulton, Michael J. Zaworotko, From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids. Chemical Reviews. ,vol. 101, pp. 1629- 1658 ,(2001) , 10.1021/CR9900432
Yu-Bin Dong, Jun-Yan Cheng, Jian-Ping Ma, Ru-Qi Huang, Mark D. Smith, Self-Assembly of {Ag2N4}-Core-Containing Coordination Polymers from AgX (X = NO3-, ClO4-, and PF6-) and Oxadiazole-Bridged 4,4‘- and 3,3‘- Biphenylamine Ligands Crystal Growth & Design. ,vol. 5, pp. 585- 591 ,(2005) , 10.1021/CG049806R
Stuart R. Batten, Richard Robson, Interpenetrating Nets: Ordered, Periodic Entanglement Angewandte Chemie International Edition. ,vol. 37, pp. 1460- 1494 ,(1998) , 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z
In Su Lee, Dong Mok Shin, Young Keun Chung, Novel supramolecular isomerism in coordination polymer synthesis from unsymmetrical bridging ligands: solvent influence on the ligand placement orientation and final network structure. Chemistry: A European Journal. ,vol. 10, pp. 3158- 3165 ,(2004) , 10.1002/CHEM.200305526
Lucia Carlucci, Gianfranco Ciani, Davide M. Proserpio, Polycatenation, polythreading and polyknotting in coordination network chemistry Coordination Chemistry Reviews. ,vol. 246, pp. 247- 289 ,(2003) , 10.1016/S0010-8545(03)00126-7