Influence of topology on the gelation behavior of coordination polymers prepared via ROMP of macrocyclic olefins
作者： Simone Albano , Alessio Fantozzi , José Augusto Berrocal , Stefano Di Stefano
DOI: 10.1002/POLA.28488
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摘要: This work reports on the consequences of concatenation two twin macrocycles gelation behavior coordination polymers obtained via ring-opening metathesis polymerization (ROMP) initiated by 2nd generation Grubbs' catalyst. The influence is evaluated comparison with a non-interlocked model complex under same reaction conditions. suitability choice discussed in terms molecular structure and effective molarity (EM). It found that has primary role process, resulting lower critical concentrations for endotopic, interlocked compared exotopic, one. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Chem. 2016, 55, 1237–1242
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