Selective hydroxylation of adamantane and its derivatives
作者： R. I. Khusnutdinov , N. A. Shchadneva , L. F. Mukhametshina , U. M. Dzhemilev
DOI: 10.1134/S1070428009080041
关键词:
摘要: A general method was developed for hydroxylation into the nodal position of adamantane and its 1- 2-substituted derivatives employing systems H2O-CBr4 (BrCCl3, CCl4) in presence complexes Pd, Ni, Ru, Co, Mo, W, Fe. The oxidants are hypochlorous (HOCl) or hypobromous (HOBr) acids generated from water halomethanes under reaction conditions.
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