A Tröger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

作者: Zhen-Zhen Yang , Hongye Zhang , Bo Yu , Yanfei Zhao , Guipeng Ji

DOI: 10.1039/C4CC08295H

关键词:

摘要: A Troger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(III) complex. The resultant TB-MOP–Ru showed good H2 adsorbing performances, high efficiency for catalysing hydrogenation of to HCOOH turnover number up 2254 at 40 °C.

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