Magnesium oxide-catalysed reaction of carbon dioxide with anepoxide with retention of stereochemistry
作者： Takashi Yano , Hideo Matsui , Takahiro Koike , Hiroyasu Ishiguro , Hisashi Fujihara
DOI: 10.1039/A608102I
关键词:
摘要: Magnesium oxide is an efficient catalyst for the cycloaddition of carbon dioxide to epoxides under mild conditions; the reaction of carbon dioxide with (R)-styrene oxide in the presence of magnesium oxide gives (R)-phenyl carbonate in 97% ee with retention of stereochemistry.
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sci-hub.se 参考文章(3)
Yasuo Fukuda, Kozo Tanabe, Infrared Study of Carbon Dioxide Adsorbed on Magnesium and Calcium Oxides Bulletin of the Chemical Society of Japan. ,vol. 46, pp. 1616- 1619 ,(1973) , 10.1246/BCSJ.46.1616
James A. Dale, Harry S. Mosher, Enantiomeric purity of phenylethylene glycol and reliability of phenylglyoxylate asymmetric reductions in configurational assignments Journal of Organic Chemistry. ,vol. 35, pp. 4002- 4003 ,(1970) , 10.1021/JO00836A109
Nobuhiro Kihara, Nobutaka Hara, Takeshi Endo, Catalytic activity of various salts in the reaction of 2,3-epoxypropyl phenyl ether and carbon dioxide under atmospheric pressure Journal of Organic Chemistry. ,vol. 58, pp. 6198- 6202 ,(1993) , 10.1021/JO00075A011