Conductive biodegradable film of N-octyloxyphenyl-N′-(4-methylbenzoyl)thiourea

作者: WAN M KHAIRUL , M I N ISA , A S SAMSUDIN , HASYIYA KARIMAH ADLI , SAIDATUL RADHIAH GHAZALI

DOI: 10.1007/S12034-014-0635-8

关键词:

摘要: Thiourea derivatives are versatile family of ligands which provides wide range electronic properties since they consist rigid π-systems on their structures. In this work, a new type thiourea compound with general formula Me-C6H4C(O)NHC(S)NHC6H4-OC8H17 N′-(4-methylbenzoyl)thiourea (MBTU) was successfully synthesised and characterized by using NMR, FTIR UV–vis analysis. The development conductive biodegradable film based MBTU has been accomplished incorporating chitosan to the polymer-dopant system via solution-cast technique. impedance measurement technique employed determine conductivity film. It shows that, addition MBTU, increasing is from 10−9 10−8 Scm−1. TNM results show that governed conducting species. proven exhibits promise great potential be explored used as doping in materials application future.

参考文章(41)
Teruo Miyamoto, Kyoichi Shibayama, Free‐volume model for ionic conductivity in polymers Journal of Applied Physics. ,vol. 44, pp. 5372- 5376 ,(1973) , 10.1063/1.1662158
Ellen Raphael, César O Avellaneda, Bruno Manzolli, Agnieszka Pawlicka, None, Agar-based films for application as polymer electrolytes Electrochimica Acta. ,vol. 55, pp. 1455- 1459 ,(2010) , 10.1016/J.ELECTACTA.2009.06.010
S.Z. Yao, F.J. He, L.H. Nie, Piezoelectric determination of traces of thiourea Analytica Chimica Acta. ,vol. 268, pp. 311- 314 ,(1992) , 10.1016/0003-2670(92)85226-V
Aneta Łukomska, Sławomir Smoliński, Jerzy Sobkowski, Adsorption of thiourea on monocrystalline copper electrodes Electrochimica Acta. ,vol. 46, pp. 3111- 3117 ,(2001) , 10.1016/S0013-4686(01)00602-8
S.R. Majid, A.K. Arof, Electrical behavior of proton-conducting chitosan-phosphoric acid-based electrolytes Physica B-condensed Matter. ,vol. 390, pp. 209- 215 ,(2007) , 10.1016/J.PHYSB.2006.08.038
M Manuela M Raposo, Ana MFP Ferreira, M Belsley, João CVP Moura, None, 5'-Alkoxy-2,2'-bithiophene azo dyes : a novel promising series of NLO-chromophores Tetrahedron. ,vol. 64, pp. 5878- 5884 ,(2008) , 10.1016/J.TET.2008.04.061
Ying Wan, Katherine A.M Creber, Brant Peppley, V.Tam Bui, Ionic conductivity of chitosan membranes Polymer. ,vol. 44, pp. 1057- 1065 ,(2003) , 10.1016/S0032-3861(02)00881-9
A.E. Bolzán, T. Iwasita, A.J. Arvia, In situ FTIRRAS study of the electro-oxidation reactions of thiourea and gold in aqueous acid solutions Journal of Electroanalytical Chemistry. ,vol. 554, pp. 49- 60 ,(2003) , 10.1016/S0022-0728(03)00050-0
M.H. Buraidah, L.P. Teo, S.R. Majid, A.K. Arof, Ionic conductivity by correlated barrier hopping in NH4I doped chitosan solid electrolyte Physica B-condensed Matter. ,vol. 404, pp. 1373- 1379 ,(2009) , 10.1016/J.PHYSB.2008.12.027