"On the Dot"-The Timing of Self-Assembled Growth to the Quantum Scale

摘要: Understanding the complex world of material growth and tunability has mystified minds scientists been met with increasing efforts to close gap between controllability applicability. The reality this journey is frustratingly tortuous but being eased through better conceptual appreciation metal crystalline frameworks that originate from shape size dependent solvent responsive patterns. quantum confinement TiO2 in range 0.8–2 nm synthetically challenging achieve lessons biomineralization processes have enabled alternative routes be explored via self-induced pre-nucleation events. In driving concept, we incorporated many these key features integrating aspects low temperature annealing at interface heterogeneous nucleation hard soft materials arrest biomimetic amorphous phase a tunable quantumized state. stabilization metastable states sized driven by kinetic thermodynamic show hallmarks biomineralized controlled events suggest inter-play new pathways interfacial energies preferentially favor dimensionality scale. This provides potential re-direct synthetic assemblies under tightly parameters generate host size, anisotropic properties as smart stimuli materials. These stabilities leading are discussed terms molecular interactions structural were previously inaccessible conventional routes. There exists an undiscovered parallel enabling unprecedented access availability novel confined parametrics design crossroads biologically only now surfacing.