Low-frequency dielectric dispersion in NaNbO3 single crystals

作者: K. Konieczny , Cz. Kajtoch

DOI: 10.1080/00150199808229550

关键词:

摘要: Abstract Dielectric measurements have been performed in NaNbO3 single crystals the frequency range 20Hz-1MHz and temperature 320K-750K. A low-frequency relaxation process is observed above phase transition point TC vicinity of TC. The obtained data were fitted to Cole-Cole formula. mean time obeys Arrhenius law dispersion step δ≈ (the maximum value δ≈2000) dependent. Both parameters: τ high discontinuity at occurrence a may be connected with disorder crystal structure already temperatures. This can lead arising local dipoles (polar regions).

参考文章(22)
Gerald Burns, F. H. Dacol, The index of refraction of BaTiO3above Tc Ferroelectrics. ,vol. 37, pp. 661- 664 ,(1981) , 10.1080/00150198108223515
I. Lefkowitz, K. Łukaszewicz, H. D. Megaw, The high-temperature phases of sodium niobate and the nature of transitions in pseudosymmetric structures Acta Crystallographica. ,vol. 20, pp. 670- 683 ,(1966) , 10.1107/S0365110X66001592
R. Comes, M. Lambert, A. Guinier, The chain structure of BaTiO3 and KNbO3 Solid State Communications. ,vol. 6, pp. 715- 719 ,(1968) , 10.1016/0038-1098(68)90571-1
Jun Chen, Duan Feng, TEM study of phases and domains in NaNbO3 at room temperature Physica Status Solidi (a). ,vol. 109, pp. 171- 185 ,(1988) , 10.1002/PSSA.2211090117
M. Ahtee, A. M. Glazer, H. D. Megaw, The structures of sodium niobate between 480° and 575°C, and their relevance to soft-phonon modes Philosophical Magazine. ,vol. 26, pp. 995- 1014 ,(1972) , 10.1080/14786437208226972
Rainer Waser, Mareike Klee, Theory of conduction and breakdown in perovskite thin films Integrated Ferroelectrics. ,vol. 2, pp. 23- 40 ,(1992) , 10.1080/10584589208215729
O. Hanske-Petitpierre, Y. Yacoby, J. Mustre de Leon, E. A. Stern, J. J. Rehr, Off-center displacement of the Nb ions below and above the ferroelectric phase transition of KTa0.91Nb0.09O3 Physical Review B. ,vol. 44, pp. 6700- 6707 ,(1991) , 10.1103/PHYSREVB.44.6700
M. Maglione, R. Böhmer, A. Loidl, U. T. Höchli, Polar relaxation mode in pure and iron-doped barium titanate Physical Review B. ,vol. 40, pp. 11441- 11444 ,(1989) , 10.1103/PHYSREVB.40.11441
B. Rechav, Y. Yacoby, E. A. Stern, J. J. Rehr, M. Newville, Local structural distortions below and above the antiferrodistortive phase transition. Physical Review Letters. ,vol. 72, pp. 1352- 1355 ,(1994) , 10.1103/PHYSREVLETT.72.1352