Synthesis and structure of the dinuclear chloro-rhodium π-complexes with vinylsilanes
作者： Paulina Błażejewska-Chadyniak , Maciej Kubicki , Hieronim Maciejewski , Bogdan Marciniec
DOI: 10.1016/S0020-1693(03)00049-5
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摘要: Abstract Reaction of the Cramer's complex [{Rh(C 2 H 4 ) (μ-Cl)} ] with appropriate vinylsilane molecules yields, by displacement ethylene ligands, complexes [{Rh(η -CH CHSiR 3 (where R =Me ( 1 ), Me Ph MePh (OSiMe 5 )). The structures , and have been determined crystalographically. There are first crystal dinuclear rhodium(I) monovinylsilanes. All characterised multinuclear NMR spectroscopy.
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sci-hub.se 参考文章(31)
John W. Fitch, William T. Osterloh, Vinylmetallics as ligands Journal of Organometallic Chemistry. ,vol. 213, pp. 493- 502 ,(1981) , 10.1016/S0022-328X(00)82955-1
Robert H. Crabtree, The organometallic chemistry of the transition metals ,(1988)
The chemistry of organic silicon compounds Wiley. ,(1989) , 10.1002/0470025107
Scott S. D. Brown, Stephen N. Heaton, Madeleine H. Moore, Robin N. Perutz, Giles Wilson, Synthesis and Photoisomerization of Divinyltetramethyldisiloxane and Divinyltetramethyldisilazane Complexes of (η5-C5R5)Rh (R = H, Me). Crystal and Molecular Structure of (η5-C5Me5)Rh[η4-(CH2CH)Me2SiOSiMe2(CHCH2)] Organometallics. ,vol. 15, pp. 1392- 1404 ,(1996) , 10.1021/OM950826N
Peter B. Hitchcock, Michael F. Lappert, Hieronim Maciejewski, A convenient route to vinylsiloxane-tertiary phosphine-nickel(0) complexes; the molecular structure of [(Ni{P(C6H4Me-4)3})2{μ-(L′′L′′)2}] {(L′′L′′)2=[CH2CH(Me)Si(μ-O)]4} Journal of Organometallic Chemistry. ,vol. 605, pp. 221- 225 ,(2000) , 10.1016/S0022-328X(00)00316-8
John W. Fitch, Kan C. Chan, Joseph A. Froelich, Vinylmetallics as ligands. VI. Preparation and stabilities of a series of vinylsilane-platinum (0) complexes Journal of Organometallic Chemistry. ,vol. 160, pp. 477- 497 ,(1978) , 10.1016/S0022-328X(00)89104-4
Peter B. Hitchcock, Michael F. Lappert, Calum MacBeath, Fiona P.E. Scott, Nicholas J.W. Warhurst, The synthesis and characterisation of some divinyldisiloxane—(tertiary phosphine) complexes of platinum(0) and nickel(0) Journal of Organometallic Chemistry. ,vol. 528, pp. 185- 190 ,(1997) , 10.1016/S0022-328X(96)06676-4
John W. Fitch, Michael Brown, Nancy H. Hall, Paul P. Mebe, Kevin A. Owens, Michael R. Roesch, Hydrolysis of allylsilanes coordinated to platinum(II) Journal of Organometallic Chemistry. ,vol. 244, pp. 201- 207 ,(1983) , 10.1016/S0022-328X(00)98602-9
Larry N. Lewis, Judith Stein, Robert E. Colborn, Yan Gao, Jun Dong, The chemistry of fumarate and maleate inhibitors with platinum hydrosilylation catalysts Journal of Organometallic Chemistry. ,vol. 521, pp. 221- 227 ,(1996) , 10.1016/0022-328X(96)06247-X
C.C. Lee, A. Piórko, R.G. Sutherland, Mono- and di-cations from ligand exchange reactions between ferrocene and some heterocyclic systems Journal of Organometallic Chemistry. ,vol. 248, pp. 357- 364 ,(1983) , 10.1016/S0022-328X(00)98717-5