Alkoxycarbonylation of olefins with carbon dioxide by a reusable heterobimetallic ruthenium–cobalt catalytic system
作者： Xuehua Zhang , Chaoren Shen , Chungu Xia , Xinxin Tian , Lin He
DOI: 10.1039/C8GC02289E
关键词:
摘要: The heterobimetallic ruthenium–cobalt catalytic system exhibited good performance and reusability in the reductive alkoxycarbonylation of olefins with carbon dioxide. Compared to previous only consisting ruthenium catalyst, binary catalyst effectively reduced usage noble metal ionic liquid additives. respective contribution cobalt catalysts this multiple-step process was investigated by a series condition-controlled experiments. evolution occurrence alkene hydrogenation during reaction explained theortical calculations.
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