Tuning Catalytic Sites on Zr6O8 Metal–Organic Framework Nodes via Ligand and Defect Chemistry Probed with tert-Butyl Alcohol Dehydration to Isobutylene
作者： Dong Yang , Carlo Alberto Gaggioli , Debmalya Ray , Melike Babucci , Laura Gagliardi
DOI: 10.1021/JACS.0C03175
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摘要: … is correlated with the catalytic activities of UiO-66, UiO-66-OH, and UiO-66-OCH 3 . Because TBA did not form tert-butoxy ligands, we suggest that it likely bonded to the open Zr sites …
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