Hauptgruppenelemente in carbonylmetallclustern

作者: Ekkehard Lindner , Gerhard A. Weiss , Wolfgang Hiller , Riad Fawzi

DOI: 10.1016/0022-328X(86)80324-2

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摘要: Abstract The cobalt clusters (μ4-S)(μ4-PR)Co4(CO)10 (R = CH3, C6H4OCH3-4) for which catalytic activity can be expected, are obtained form the thioxophosphoranes RP(S)Cl2 and Na[Co(CO)4] in ether with cleavage of PS bond. compound R  C6H4OCH3-4, crystallizes triclinic space group P 1 Z 4.

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