Preparation and Characterization of Single-Modified TiO2 for Pigmentary Applications
作者： Barbara Grzmil , Marta Gleń , Bogumił Kic , Krzysztof Lubkowski
DOI: 10.1021/IE1016078
关键词:
摘要: In the present work influence of different additives, calculated to ZrO2, ZnO, and B2O3, on anatase–rutile phase transformation was investigated. The chemical composition prepared titania samples determined by selective leaching method, powder X-ray diffraction analysis, FT-IR measurements. effect small amounts additives optical properties, photoactivity, surface area rutile-phased TiO2 for pigmentary applications examined using spectrophotometer, SEM, BET ZrO2 acted as an inhibitor addition ZnO or B2O3 accelerated rutile formation at 750 °C. in could form separate solid solution Zr with Ti. Zinc partly reacted titanium forming cophase TiZn2O4. Boron located soluble compound, B2O3. Almost all properties were lower modified comparison corresponding unmodified sample. SBET increased ...
acs.org
sci-hub.se 参考文章(36)
F. C. Gennari, D. M. Pasquevich, Kinetics of the anatase–rutile transformation in TiO2 in the presence of Fe2O3 Journal of Materials Science. ,vol. 33, pp. 1571- 1578 ,(1998) , 10.1023/A:1017515804370
Najeh I. Al-Salim, Stephen A. Bagshaw, Antoine Bittar, Tim Kemmitt, A. James McQuillan, Ann M. Mills, Martin J. Ryan, Characterisation and activity of sol–gel-preparedTiO2 photocatalysts modified with Ca, Sr or Ba ion additives Journal of Materials Chemistry. ,vol. 10, pp. 2358- 2363 ,(2000) , 10.1039/B004384M
G. Colón, J.M. Sánchez-España, M.C. Hidalgo, J.A. Navío, Effect of TiO2 acidic pre-treatment on the photocatalytic properties for phenol degradation Journal of Photochemistry and Photobiology A: Chemistry. ,vol. 179, pp. 20- 27 ,(2006) , 10.1016/J.JPHOTOCHEM.2005.07.007
V. Brezová, A. Blažková, Ľ. Karpinský, J. Grošková, B. Havlínová, V. Jorík, M. Čeppan, Phenol decomposition using Mn+/TiO2 photocatalysts supported by the sol-gel technique on glass fibres Journal of Photochemistry and Photobiology A: Chemistry. ,vol. 109, pp. 177- 183 ,(1997) , 10.1016/S1010-6030(97)00121-4
J Yang, J.M.F Ferreira, On the Titania Phase Transition by Zirconia Additive in a Sol-Gel-Derived Powder Materials Research Bulletin. ,vol. 33, pp. 389- 394 ,(1998) , 10.1016/S0025-5408(97)00249-3
Barbara Grzmil, Magdalena Rabe, Bogumił Kic, Krzysztof Lubkowski, Influence of Phosphate, Potassium, Lithium, and Aluminium on the Anatase−Rutile Phase Transformation Industrial & Engineering Chemistry Research. ,vol. 46, pp. 1018- 1024 ,(2007) , 10.1021/IE060188G
K. Wilke, H.D. Breuer, The influence of transition metal doping on the physical and photocatalytic properties of titania Journal of Photochemistry and Photobiology A-chemistry. ,vol. 121, pp. 49- 53 ,(1999) , 10.1016/S1010-6030(98)00452-3
Yu-Hong Zhang, Armin Reller, Phase transformation and grain growth of doped nanosized titania Materials Science and Engineering: C. ,vol. 19, pp. 323- 326 ,(2002) , 10.1016/S0928-4931(01)00409-X
Daimei Chen, Dong Yang, Qun Wang, Zhongyi Jiang, Effects of Boron Doping on Photocatalytic Activity and Microstructure of Titanium Dioxide Nanoparticles Industrial & Engineering Chemistry Research. ,vol. 45, pp. 4110- 4116 ,(2006) , 10.1021/IE0600902
László Kőrösi, Imre Dékány, Preparation and investigation of structural and photocatalytic properties of phosphate modified titanium dioxide Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 280, pp. 146- 154 ,(2006) , 10.1016/J.COLSURFA.2006.01.052