Reductive Dehydration of Ethanol: A New Route Towards Alkanes
作者： M. V. Tsodikov , F. A. Yandieva , V. Ya. Kugel , A. V. Chistyakov , A. E. Gekhman
DOI: 10.1007/S10562-007-9347-7
关键词:
摘要: New reactions, catalytic ethanol reductive dehydration into alkanes C3–C10 and cross-coupling of with cyclopentanol alkyl substituted cycloalkanes, were studied. The was carried out at 350 °C 50 atm Ar. intermetallic hydrides different hydrogen content, industrial Pt/γ-Al2O3 reduced molten promoted iron catalysts used as catalysts. yield varies depending on acid/base additives. conversion the higher increase content in material decreases. When MgO is additive converts mainly iso-alkanes. iso-alkanes C5–C10 fraction reaches 92%. over compositions consisting hydride afforded cyclic hydrocarbons.
springer.com
sci-hub.se 参考文章(17)
Carlo Carlini, Marco Di Girolamo, Alessandro Macinai, Mario Marchionna, Marilena Noviello, Anna Maria Raspolli Galletti, Glauco Sbrana, Selective synthesis of isobutanol by means of the Guerbet reaction Part 2. Reaction of methanol/ethanol and methanol/ethanol/n-propanol mixtures over copper based/MeONa catalytic systems Journal of Molecular Catalysis A-chemical. ,vol. 200, pp. 137- 146 ,(2003) , 10.1016/S1381-1169(03)00042-6
DI Kochubei, VV Kriventsov, Yu V Maksimov, MV Tsodikov, FA Yandieva, VP Mordvin, JA Navio, II Moiseev, Intermetallic Hydrides [TiFe 0.95 Zr 0.03 Mo 0.02 ]H x (0 ≤ x ≤ 2): The Nature of the Phase Responsible for the Selective Reduction of CO 2 Kinetics and Catalysis. ,vol. 44, pp. 165- 174 ,(2003) , 10.1023/A:1023392126234
Charles La Mar Thomas, Catalytic processes and proven catalysts Academic Press. ,(1970)
Melvin Jensen Astle, The chemistry of petrochemicals Reinhold. ,(1956)
G. C. Bond, Vladimír Ponec, Catalysis by metals and alloys Elsevier. ,(1995)
M.V. Tsodikov, V.Ya. Kugel, F.A. Yandieva, E.V. Slivinskii, I.I. Moiseev, G. Colón, M.C. Hidalgo, J.A. Navío, CH4 and CO2 transformations initiated by hydrogen-accumulated systems. Role of spillover and lattice bound hydrogen Studies in Surface Science and Catalysis. ,vol. 138, pp. 239- 250 ,(2001) , 10.1016/S0167-2991(01)80035-5
Hans-Jürgen Arpe, Klaus Weissermel, Industrial Organic Chemistry ,(1978)
Jerry March, Advanced Organic Chemistry: Reactions, Mechanisms, and Structure ,(1977)
Boy Cornils, Wolfgang A. Herrmann, Robert Schlögl, Chi-Huey Wong, Catalysis from A to Z: A Concise Encyclopedia ,(2020)
Carlo Carlini, Marco Di Girolamo, Mario Marchionna, Marilena Noviello, Anna Maria Raspolli Galletti, Glauco Sbrana, Selective synthesis of isobutanol by means of the Guerbet reaction - Part 1. Methanol/n-propanol condensation by using copper based catalytic systems Journal of Molecular Catalysis A-chemical. ,vol. 184, pp. 273- 280 ,(2003) , 10.1016/S1381-1169(02)00007-9