Cation-exchange membranes: Comparison of homopolymer, block copolymer, and heterogeneous membranes
作者： Jan Schauer , Javier Llanos , Jan Žitka , Jaromír Hnát , Karel Bouzek
DOI: 10.1002/APP.35524
关键词:
摘要: Three types of sulfonic cation-exchange membranes were compared: (a) homogenous prepared by sulfonation poly(2,6-dimethyl-1,4-phenylene oxide) or poly[oxy(1,4-phenylene)oxy(1,4-phenylene)carbonyl(1,4-phenylene)] and solution casting the sulfonated products, (b) poly [styrene-block-(ethene-stat-butene)-block-styrene] film, (c) heterogeneous melt-blending linear polyethylene particles 10–25 μm cation-exchanger followed compression molding. At same ion-exchange capacity (IEC), based on block copolymer showed considerably higher ionic conductivity than homogeneous membranes. Though having a IEC, less conductive other investigated Their advantage consists in ease preparation superior resistance to oxidative environment. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
sci-hub.se 参考文章(40)
A. Navarro, C. del Río, J.L. Acosta, Kinetic study of the sulfonation of hydrogenated styrene butadiene block copolymer (HSBS): Microstructural and electrical characterizations Journal of Membrane Science. ,vol. 300, pp. 79- 87 ,(2007) , 10.1016/J.MEMSCI.2007.05.009
Hirokazu Hasegawa, Hideaki Tanaka, Komei Yamasaki, Takeji Hashimoto, Bicontinuous microdomain morphology of block copolymers. 1. Tetrapod-network structure of polystyrene-polyisoprene diblock polymers Macromolecules. ,vol. 20, pp. 1651- 1662 ,(1987) , 10.1021/MA00173A036
J SCHAUER, L BROZOVA, Heterogeneous ion-exchange membranes based on sulfonated poly(1,4-phenylene sulfide) and linear polyethylene: preparation, oxidation stability, methanol permeability and electrochemical properties Journal of Membrane Science. ,vol. 250, pp. 151- 157 ,(2005) , 10.1016/J.MEMSCI.2004.09.047
Peixiang Xing, Gilles P Robertson, Michael D Guiver, Serguei D Mikhailenko, Keping Wang, Serge Kaliaguine, Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes Journal of Membrane Science. ,vol. 229, pp. 95- 106 ,(2004) , 10.1016/J.MEMSCI.2003.09.019
Barbara Kosmala, Jan Schauer, Ion‐exchange membranes prepared by blending sulfonated poly(2,6‐dimethyl‐1,4‐phenylene oxide) with polybenzimidazole Journal of Applied Polymer Science. ,vol. 85, pp. 1118- 1127 ,(2002) , 10.1002/APP.10632
Xigao Jin, Matthew T. Bishop, Thomas S. Ellis, Frank E. Karasz, A sulphonated poly(aryl ether ketone) British Polymer Journal. ,vol. 17, pp. 4- 10 ,(1985) , 10.1002/PI.4980170102
J CHEN, M ASANO, Y MAEKAWA, M YOSHIDA, Suitability of some fluoropolymers used as base films for preparation of polymer electrolyte fuel cell membranes Journal of Membrane Science. ,vol. 277, pp. 249- 257 ,(2006) , 10.1016/J.MEMSCI.2005.10.036
C. Iojoiu, M. Maréchal, F. Chabert, J.-Y. Sanchez, Mastering Sulfonation of Aromatic Polysulfones: Crucial for Membranes for Fuel Cell Application† Fuel Cells. ,vol. 5, pp. 344- 354 ,(2005) , 10.1002/FUCE.200400082
Zongwu Bai, Marlene D. Houtz, Peter A. Mirau, Thuy D. Dang, Structures and properties of highly sulfonated poly(arylenethioethersulfone)s as proton exchange membranes Polymer. ,vol. 48, pp. 6598- 6604 ,(2007) , 10.1016/J.POLYMER.2007.08.052
Tomohiro Yasuda, Yi Li, Kenji Miyatake, Michiko Hirai, Masato Nanasawa, Masahiro Watanabe, Synthesis and properties of polyimides bearing acid groups on long pendant aliphatic chains Journal of Polymer Science Part A. ,vol. 44, pp. 3995- 4005 ,(2006) , 10.1002/POLA.21509