Introduction to Polymer Science and Chemistry : A Problem-Solving Approach

摘要: Introductory Concepts Basic Definitions Polymerization and Functionality Processes Molecular Architecture Classification of Polymers Plastics, Fibers, Elastomers Polymer Nomenclature References Exercises Chain Dimensions, Structures, Transitional Phenomena Introduction PolymerChains: Structures Dimensions Constitutional Configurational Isomerism Crystallinity in Thermal Transitions Regions Viscoelastic Behavior Factors Affecting Tg Tm Relation Between Theoretical Treatment Glass Transition Movements Amorphous State Thermodynamics Rubber Elasticity Solution Phase Equilibria Poor Solvents Solubility Swelling Crosslinked Frictional Properties Molecules Dilute Weights Weight Averages Terms Moments Determination Condensation (Step-Growth) Rates Polycondensation Reactions Number-Average Degree Control Distribution (MWD) Nonlinear Step Recursive Approach for Average AxB Monomers Free Radical Scheme Experimental Rp : Dilatometry Methods Initiation Dead-End Absolute Rate Constants Length Transfer Deviations from Ideal Kinetics Inhibition/Retardation Effects Temperature Living Copolymerization Binary Copolymer Composition - Terminal Model Multicomponent Copolymerization: Terpolymerization Crosslinking Block Graft Reference Ionic Polymerizability Anionic Cationic Coordination Addition Ziegler-Natta Catalysts Mechanism Supported Metal Oxide Metallocene-Based Immobilized Metallocene Oscillating Ring-Opening Living/Controlled Stable Atom (ATRP) Degenerative Reversible Addition-Fragmentation Synthesis by Click Chemistry Copper-Catalyzed Azide-Alkyne Cycloaddition Strain-Promoted Coupling Diels-Alder Thiol-Ene Appendix A Conversion Units B Fundamental Index