Analytical method for the quantitative determination of cyanuric acid as the degradation product of sodium dichloroisocyanurate in urine by liquid chromatography mass spectrometry.
作者： Katan Patel , Kate Jones
DOI: 10.1016/J.JCHROMB.2007.03.014
关键词:
摘要: A simple and selective analytical method for the quantitative determination of cyanuric acid, degradation product sodium dichloroisocyanurate (NaDCC), in human urine is reported herein. The sample preparation involved use diatomaceous earth extraction columns. Quantification was achieved by liquid chromatography mass spectrometry using negative ion electrospray with a cyano (CN) column. Between day relative standard deviation less than 10% (n=6) obtained at 5 mg L(-1) level. assay linear over investigated range 0-20 limit detection (LOD) confirmed to be 0.1 L(-1). applied monitoring levels acid healthcare workers disinfectants products containing NaDCC.
elsevier.com
sci-hub.se 参考文章(8)
B G Hammond, S J Barbee, T Inoue, N Ishida, G J Levinskas, M W Stevens, A G Wheeler, T Cascieri, A review of toxicology studies on cyanurate and its chlorinated derivatives. Environmental Health Perspectives. ,vol. 69, pp. 287- 292 ,(1986) , 10.1289/EHP.8669287
Ricardo Cantú, Otis Evans, Fred K. Kawahara, Jody A. Shoemaker, Alfred P. Dufour, An HPLC method with UV detection, pH control, and reductive ascorbic acid for cyanuric acid analysis in water. Analytical Chemistry. ,vol. 72, pp. 5820- 5828 ,(2000) , 10.1021/AC0005868
Ricardo Cantú, Otis Evans, Fred K. Kawahara, Larry J. Wymer, Alfred P. Dufour, HPLC Determination of Cyanuric Acid in Swimming Pool Waters Using Phenyl and Confirmatory Porous Graphitic Carbon Columns Analytical Chemistry. ,vol. 73, pp. 3358- 3364 ,(2001) , 10.1021/AC001412T
Matthew L. Magnuson, Catherine A. Kelty, Ricardo Cantú, Stable association complex electrospray mass spectrometry for the determination of cyanuric acid. Journal of the American Society for Mass Spectrometry. ,vol. 12, pp. 1085- 1091 ,(2001) , 10.1016/S1044-0305(01)00292-6
D Coates, Use of sodium dichloroisocyanurate granules for spills of body fluids Journal of Hospital Infection. ,vol. 13, pp. 241- 251 ,(1989) , 10.1016/0195-6701(89)90004-2
SALLY F. BLOOMFIELD, GWYNEDD A. MILES, The antibacterial properties of sodium dichloroisocyanurate and sodium hypochlorite formulations Journal of Applied Microbiology. ,vol. 46, pp. 65- 73 ,(1979) , 10.1111/J.1365-2672.1979.TB02582.X
Larry M. Allen, Thomas V. Briggle, Carl D. Pfaffenberger, Absorption and Excretion of Cyanuric Acid in Long-Distance Swimmers Drug Metabolism Reviews. ,vol. 13, pp. 499- 516 ,(1982) , 10.3109/03602538209029992
Yiannis C. Fiamegos, Constantina N. Konidari, Constantine D. Stalikas, Cyanuric acid trace analysis by extractive methylation via phase-transfer catalysis and capillary gas chromatography coupled with flame thermoionic and mass-selective detection. Process parameter studies and kinetics. Analytical Chemistry. ,vol. 75, pp. 4034- 4042 ,(2003) , 10.1021/AC030057E