Polymer–metal complex as gel electrolyte for quasi-solid-state dye-sensitized solar cells
作者： Wanchun Xiang , Yanyan Fang , Yuan Lin , Shibi Fang
DOI: 10.1016/J.ELECTACTA.2010.10.061
关键词:
摘要: a kind of polymer-metal complex gel electrolyte is successfully prepared and used in dye-sensitized solar cells. raman x-ray photoelectron spectroscopy confirm the structure this found that metal ion reacts with nitrogen polymer. novel shows apparent diffusion coefficient iodide 8.37 x 10(-7) cm(2) s(-1) energy conversion efficiency 6.10% when amount znl(2) 0.04 m. by studying dissociation active inorganic salt electrolytes, we find salts can dissociate more easily after reacting polymer as result provide extra free ion. cell maintains ca. 93% its initial 20 d without further sealing, which good long-time stability. crown copyright (c) 2010 published elsevier ltd. all rights reserved.
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Shinji Murai, Satoshi Mikoshiba, Hiroyasu Sumino, Shuzi Hayase, Quasi-solid dye-sensitized solar cells containing chemically cross-linked gel Journal of Photochemistry and Photobiology A: Chemistry. ,vol. 148, pp. 33- 39 ,(2002) , 10.1016/S1010-6030(02)00046-1
Brian O'Regan, Daniel T. Schwartz, Efficient photo-hole injection from adsorbed cyanine dyes into electrodeposited copper(I) thiocyanate thin films Chemistry of Materials. ,vol. 7, pp. 1349- 1354 ,(1995) , 10.1021/CM00055A012
Daryle Fish, Ishrat M. Khan, Johannes Smid, Conductivity of solid complexes of lithium perchlorate with poly{[ω‐methoxyhexa(oxyethylene)ethoxy]methylsiloxane} Die Makromolekulare Chemie, Rapid Communications. ,vol. 7, pp. 115- 120 ,(1986) , 10.1002/MARC.1986.030070303
V. P. S. Perera, P. K. D. D. P. Pitigala, P. V. V. Jayaweera, K. M. P. Bandaranayake, K. Tennakone, Dye-Sensitized Solid-State Photovoltaic Cells Based on Dye Multilayer−Semiconductor Nanostructures Journal of Physical Chemistry B. ,vol. 107, pp. 13758- 13761 ,(2003) , 10.1021/JP0348979
Noriyo Yamanaka, Ryuji Kawano, Wataru Kubo, Naruhiko Masaki, Takayuki Kitamura, Yuji Wada, Masayoshi Watanabe, Shozo Yanagida, Dye-sensitized TiO2 solar cells using imidazolium-type ionic liquid crystal systems as effective electrolytes. Journal of Physical Chemistry B. ,vol. 111, pp. 4763- 4769 ,(2007) , 10.1021/JP0671446
Moon-Sung Kang, Kwang-Soon Ahn, Ji-Won Lee, Quasi-solid-state dye-sensitized solar cells employing ternary component polymer-gel electrolytes Journal of Power Sources. ,vol. 180, pp. 896- 901 ,(2008) , 10.1016/J.JPOWSOUR.2008.02.087
Mohammad K. Nazeeruddin, Filippo De Angelis, Simona Fantacci, Annabella Selloni, Guido Viscardi, Paul Liska, Seigo Ito, Bessho Takeru, Michael Grätzel, Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers Journal of the American Chemical Society. ,vol. 127, pp. 16835- 16847 ,(2005) , 10.1021/JA052467L
Jong Hyuk Park, Kyu Jin Choi, Sang Wook Kang, Yong Soo Kang, Junkyung Kim, Sang-Soo Lee, Solid-state oligomer electrolyte with amine–acid interaction for dye-sensitized solar cells Journal of Power Sources. ,vol. 183, pp. 812- 816 ,(2008) , 10.1016/J.JPOWSOUR.2008.05.040
Hongxia Wang, Hong Li, Bofei Xue, Zhaoxiang Wang, Qingbo Meng, Liquan Chen, Solid-state composite electrolyte LiI/3-hydroxypropionitrile/SiO2 for dye-sensitized solar cells Journal of the American Chemical Society. ,vol. 127, pp. 6394- 6401 ,(2005) , 10.1021/JA043268P
Mingkui Wang, Carole Grätzel, Soo-Jin Moon, Robin Humphry-Baker, Nathalie Rossier-Iten, Shaik M. Zakeeruddin, Michael Grätzel, Surface Design in Solid‐State Dye Sensitized Solar Cells: Effects of Zwitterionic Co‐adsorbents on Photovoltaic Performance Advanced Functional Materials. ,vol. 19, pp. 2163- 2172 ,(2009) , 10.1002/ADFM.200900246