Oxidation of saturated and unsaturated alcohols promoted by aluminum alkyls and t-butyl hydroperoxide
作者： Antonio Proto , Carmine Capacchione , Arrigo Scettri , Oriana Motta
DOI: 10.1016/S0926-860X(03)00081-4
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摘要: Saturated and unsaturated alcohols are efficiently converted into the corresponding ketones epoxy-alcohols by treatment with organic aluminium compounds/t-butyl hydroperoxide systems. In this paper, we have exploited possibility of using some commercial alkyls as catalysts for oxidation reactions. Then, since observed that increase hindrance on enhances conversion toward oxidated products, found interest to synthesize a more hindered based compound. The catalytic performance latter compound reactions allylic was tested it is most attractive both in terms yield time reaction.
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