Synthesis and characterization of molybdenum(0) and tungsten(0) carbonyl derivatives of methylenebis[diphenylphosphine oxide] and bis[(diphenylphosphinyl)methyl]phenylphosphine Oxide
作者： P. Planinić , H. Meider
DOI: 10.1016/S0277-5387(00)83824-3
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摘要: Abstract The reaction of molybdenum and tungsten hexacarbonyls with the ligands [(C 6 H 5 ) 2 P(O)] CH (MDPO) P(O)CH ] P(O)C , (RPPh) has been investigated. new compounds cis -M(CO) 4 MDPO, RPPh, fac -M (CO) 3 where M = Mo 0 or W have prepared. All complexes isolated are diamagnetic an octahedral geometry. Results IR, Raman NMR spectra discussed.
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