Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine
作者： Yaxian Yuan , Jianlin Yao , Jun Lu , Yong Zhang , Renao Gu
DOI: 10.1016/J.INOCHE.2005.08.006
关键词:
摘要: Abstract A new chiral binuclear copper(II) complex of (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine (S-dmpmpH) was prepared by direct electrochemical oxidation Cu electrode in acetonitrile solutions. The final product, Cu2(S-dmpmp)2Cl(μ-OH) crystallized and characterized microanalysis, Raman spectroscopy together with X-ray crystallographic determinations.
unirioja.es
elsevier.com
sci-hub.se 参考文章(20)
H. Brunner, T. Chuard, Asymmetric catalysis, part 91: Enantioselective monophenylation ofcis-1,2-cyclopentanediol with triphenylbismuth diacetate and chiral copper(II) complexes as catalysts Monatshefte Fur Chemie. ,vol. 125, pp. 1293- 1300 ,(1994) , 10.1007/BF00811078
Ángeles Gama, Lucı́a Z. Flores-López, Gerardo Aguirre, Miguel Parra-Hake, Ratnasamy Somanathan, Thomas Cole, A study of substituent effects on the enantioselective trimethylsilylcyanation of benzaldehyde catalyzed by chiral Schiff base–titanium(IV) complexes Tetrahedron-asymmetry. ,vol. 16, pp. 1167- 1174 ,(2005) , 10.1016/J.TETASY.2005.01.030
Gu Jiansheng, Yuan Yaxian, Li Baolong, Qian HuiFen, Dennis G. Tuck, Direct Electrochemical Synthesis and Characterization of Samarium(III) and Neodymium(III) Complexes with 2-Hydroxy-2,4,6-cycloheptatrienone (Tropolone) Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. ,vol. 27, pp. 1249- 1259 ,(1997) , 10.1080/00945719708000156
Klaus Bernauer, Simona Ghizdavu, Luca Verardo, Chiral metal complexes as probes in electron-transfer reactions involving metalloproteins Coordination Chemistry Reviews. ,vol. 190, pp. 357- 369 ,(1999) , 10.1016/S0010-8545(99)00094-6
A. Kudelski, W. Grochala, M. Janik-Czachor, J. Bukowska, A. Szummer, M. Dolata, Surface‐enhanced Raman scattering (SERS) at Copper(I) oxide Journal of Raman Spectroscopy. ,vol. 29, pp. 431- 435 ,(1998) , 10.1002/(SICI)1097-4555(199805)29:5<431::AID-JRS260>3.0.CO;2-S
E. GASSMANN, J. E. KUO, R. N. ZARE, Electrokinetic separation of chiral compounds. Science. ,vol. 230, pp. 813- 814 ,(1985) , 10.1126/SCIENCE.230.4727.813
Shulin Zhao, Yi-Ming Liu, Enantioseparation of underivatized amino acids by capillary electrophoresis using copper(II)-(S)-3-aminopyrrolidine-L-histidine ternary complex as the chiral selector Analytica Chimica Acta. ,vol. 426, pp. 65- 70 ,(2001) , 10.1016/S0003-2670(00)01170-3
R. Noyori, S. Suga, K. Kawai, S. Okada, M. Kitamura, N. Oguni, M. Hayashi, T. Kaneko, Y. Matsuda, Enantioselective addition of diorganozincs to aldehydes catalyzed by β-amino alcohols Journal of Organometallic Chemistry. ,vol. 382, pp. 19- 37 ,(1990) , 10.1016/0022-328X(90)85212-H
Jiaxi Xu, A new and expeditious asymmetric synthesis of (R)- and (S)-2-aminoalkanesulfonic acids from chiral amino alcohols Tetrahedron: Asymmetry. ,vol. 13, pp. 1129- 1134 ,(2002) , 10.1016/S0957-4166(02)00312-9
Yongcun Shen, Xiaoming Feng, Yan Li, Guolin Zhang, Yaozhong Jiang, Asymmetric Cyanosilylation of Ketones Catalyzed by Bifunctional Chiral N‐Oxide Titanium Complex Catalysts European Journal of Organic Chemistry. ,vol. 2004, pp. 129- 137 ,(2004) , 10.1002/EJOC.200300415