Optimization of NASICON composition for Na+ recognition
作者： H. Khireddine , P. Fabry , A. Caneiro , B. Bochu
DOI: 10.1016/S0925-4005(97)80266-3
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摘要: Abstract Na 1+ x Zr 2 Si P 3−x O 12 are ceramic materials which fast ionic conductors by + . The present work concerns the characterizations of such in range = 1.4–3.0 for their use as ion sensitive membranes. Samples were prepared sol-gel route to obtain pellets with a high density. Characteristics, lattice parameters and bulk conductivity given. Results on detection limit selectivity membranes used ISE devices presented. effect stoichiometry electrochemical characteristics is discussed. best performances obtained 2.0–2.2, samples sintered at 1200°C. No influence sintering temperature noticeable selectivity, excepted proton less interfering after
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