Influence of solvent on the structural and morphological properties of AgI particles prepared using ultrasonic spray pyrolysis
作者： Ivana Lj.Validžić , Vukoman Jokanović , Dragan P. Uskoković , Jovan M. Nedeljković
DOI: 10.1016/J.MATCHEMPHYS.2007.06.035
关键词:
摘要: Silver iodide particles were synthesized in the process of ultrasonic spray pyrolysis using aqueous solutions thermodynamically stable silver clusters as precursor. The AgI collected solvents different polarities such water, 2-propanol and toluene. In order to study influence solvent aging time on morphological structural properties ultra-filtration was employed isolate solid material from solution. scanning electron microscopy showed that morphology is for solvents. with hexagonal/triangular shape obtained water toluene, while hollow spheres formed. X-ray diffraction analysis, besides wurtzite hexagonal zinc blende cubic phases, revealed appearance tetragonal high-pressure modification sample toluene aged 2-propanol. induced transformation all three modifications into single phase one preferred orientation.
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sci-hub.se 参考文章(29)
X.M. Lin, C.M. Sorensen, K.J. Klabunde, Digestive Ripening, Nanophase Segregation and Superlattice Formation in Gold Nanocrystal Colloids Journal of Nanoparticle Research. ,vol. 2, pp. 157- 164 ,(2000) , 10.1023/A:1010078521951
O. I. Micic, M. T. Nenadovic, T. Rajh, J. M. Nedeljkovic, M. I. Vucemilovic, Kinetic and spectroscopic properties of small colloids of metal iodide semiconductors Steinkopff. pp. 20- 23 ,(1988) , 10.1007/BFB0114162
Shuichi Hamada, Egon Matijević, Formation of monodispersed colloidal cubic haematite particles in ethanol + water solutions Journal of the Chemical Society, Faraday Transactions. ,vol. 78, pp. 2147- 2156 ,(1982) , 10.1039/F19827802147
Jovan M. Nedeljkovic, Rajna Herak, Olga I. Micic, Early Stages of HgI2 Aggregation in Aqueous Solution Langmuir. ,vol. 8, pp. 299- 302 ,(1992) , 10.1021/LA00037A054
Chester R. Berry, Structure and Optical Absorption of AgI Microcrystals Physical Review. ,vol. 161, pp. 848- 851 ,(1967) , 10.1103/PHYSREV.161.848
Paul Mulvaney, Nucleation and stabilization of quantized AgI clusters in aqueous solution Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 81, pp. 231- 238 ,(1993) , 10.1016/0927-7757(93)80250-I
K. H. Schmidt, R. Patel, Dan. Meisel, Growth of silver halides from the molecule to the crystal. A pulse radiolysis study Journal of the American Chemical Society. ,vol. 110, pp. 4882- 4884 ,(1988) , 10.1021/JA00223A002
D A Keen, S Hull, A powder neutron diffraction study of the pressure-induced phase transitions within silver iodide Journal of Physics: Condensed Matter. ,vol. 5, pp. 23- 32 ,(1993) , 10.1088/0953-8984/5/1/005
Vukoman Jokanović, B Jokanović, Jovan Nedeljković, Olivera Milošević, None, Modeling of nanostructured TiO2 spheres obtained by ultrasonic spray pyrolysis Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 249, pp. 111- 113 ,(2004) , 10.1016/J.COLSURFA.2004.08.059
Yinhai Wang, Jimei Mo, Weili Cai, Lianzeng Yao, Lide Zhang, Synthesis of nano-AgI arrays and their optical properties Journal of Materials Research. ,vol. 16, pp. 990- 992 ,(2001) , 10.1557/JMR.2001.0139