An imperfect packing of CCl4 molecules confined in a graphic slit nanospace

作者: T. Iiyama , T. Suzuki , K. Kaneko

DOI: 10.1016/0009-2614(96)00716-6

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摘要: Abstract The intermolecular structures of CCl 4 in slit-shaped graphitic micropores having different pore widths 0.75 to 1.13 nm were determined with the electron radial distribution function (ERDF) using sity X-ray diffraction data at 303 K. peak position ERDF confined was basically similar that bulk liquid, but feature for depending on width. Although distributions nearest third neighbors less than those second neighbor shifted shorter distance. Furthermore, presence an unusual molecules width, which arises from serious restriction molecular packing evidenced.

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