A Carbene-Stabilized Gold(I) Fluoride: Synthesis and Theory
作者： David S. Laitar , Peter Müller , Thomas G. Gray , Joseph P. Sadighi
DOI: 10.1021/OM050619F
关键词:
摘要: The first isolable gold(I) fluoride complex, stabilized by an N-heterocyclic carbene (NHC) ligand, has been isolated in two-coordinate monomeric form. DFT calculations show significant pπ/dπ interactions between and indicate a substantial negative charge on fluorine.
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