Negative Muon Chemistry: The Quantum Muon Effect and the Finite Nuclear Mass Effect

摘要: The any-particle molecular orbital method at the full configuration interaction level has been employed to study atoms in which one electron replaced by a negative muon. In this approach electrons and muons are described as quantum waves. A scheme proposed discriminate nuclear mass muon effects on chemical properties of muonic regular atoms. This reveals that differences ionization potentials isoelectronic order millielectronvolts. For valence ionizations helium lithium more important. On other hand, for 1s heavier than beryllium, addition, presents an assessment barrier Heμ + H2 reaction.