Effect of the Coupling with Frenkel States on the Electroaborption Signal of Charge Transfer Excitons

作者: Michal Slawik , Piotr Petelenz

DOI: 10.1080/10587259808047156

关键词:

摘要: Abstract The recently proposed nearest-neighbour model of the coupling between Frenkel and charge transfer (CT) excitations a molecular crystal, successfully applied for calculation electroabsorption (EA) spectra polyacenes fullerene, is to probe influence different intramolecular excited states on EA signal in CT energy range. study highlights pre-eminent role excitons that are energetically close manifold, even if they inactive conventional absorption spectroscopy. high-energy intense found have lesser effect. suggests spectroscopy as potential tool detect locate some absorption-inactive excitations.

参考文章(12)
Piotr Petelenz, Michal/ Slawik, Kohei Yokoi, Marek Z. Zgierski, Theoretical calculation of the electroabsorption spectra of polyacene crystals Journal of Chemical Physics. ,vol. 105, pp. 4427- 4440 ,(1996) , 10.1063/1.472295
M. Muccini, R. Danieli, R. Zamboni, C. Taliani, H. Mohn, W. Müller, H.U. ter Meer, Location of the lowest exciton in C60 single crystal by two-photon excitation spectroscopy Chemical Physics Letters. ,vol. 245, pp. 107- 112 ,(1995) , 10.1016/0009-2614(95)00973-8
Piotr Petelenz, Michał Slawik, Barbara Pac, Electro-absorption spectrum of buckminsterfullerene — evidence for the existence of charge transfer states Synthetic Metals. ,vol. 64, pp. 335- 339 ,(1994) , 10.1016/0379-6779(94)90133-3
L. Sebastian, G. Weiser, H. Bässler, Charge transfer transitions in solid tetracene and pentacene studied by electroabsorption Chemical Physics. ,vol. 61, pp. 125- 135 ,(1981) , 10.1016/0301-0104(81)85055-0
S. Jeglinski, Z.V. Vardeny, D. Moses, V.I. Srdanov, F. Wudl, Electroabsorption studies of undoped C60 thin films Synthetic Metals. ,vol. 50, pp. 557- 563 ,(1992) , 10.1016/0379-6779(92)90213-3
M. Pilch, M. Pawilikowski, O.Sonnich Mortensen, Magnetic circular dichroism (MCD) study of low-energy 1Ag→1T1u transitions in fullerene Chemical Physics. ,vol. 172, pp. 277- 283 ,(1993) , 10.1016/0301-0104(93)80122-P
Z. Gasyna, P.N. Schatz, J.P. Hare, T.J. Dennis, H.W. Kroto, R. Taylor, D.R.M. Walton, The magnetic circular dichroism and absorption spectra of C60 isolated in Ar matrices Chemical Physics Letters. ,vol. 183, pp. 283- 291 ,(1991) , 10.1016/0009-2614(91)80064-5
Fabrizia Negri, Giorgio Orlandi, Francesco Zerbetto, Interpretation of the vibrational structure of the emission and absorption spectra of C60 Journal of Chemical Physics. ,vol. 97, pp. 6496- 6503 ,(1992) , 10.1063/1.463982
L. Sebastian, G. Weiser, G. Peter, H. Bässler, Charge-transfer transitions in crystalline anthracene and their role in photoconductivity Chemical Physics. ,vol. 75, pp. 103- 114 ,(1983) , 10.1016/0301-0104(83)85012-5
Piotr Petelenz, Nonlocal polarizabilities in excited states of polyacene crystals Chemical Physics Letters. ,vol. 215, pp. 607- 610 ,(1993) , 10.1016/0009-2614(93)89364-N